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Development of New Al-Cu Based Alloys Aimed at Improving the Machinability of Automotive Castings

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Abstract

This paper presents the first part of a study aimed at improving the machinability of a new Al-Cu based alloy containing very low silicon content, and intended for automotive applications. The results reported here focus on the development of the tensile properties of the alloy. This was achieved through the improvement of both casting and mechanical properties using melt treatments, alloy element additions, and heat treatment techniques. Various alloys were prepared to investigate the effects of Sr, TiB2, Fe, Mn, Ag, Sn and Zr additions on the tensile properties in the T6-and T7-tempered conditions, the intent being to use the data obtained to select the best alloy candidates for machinability studies. The results show that the T6 treatment provides the best tensile properties. Due to the low Si content, the effect of Sr modification on the tensile properties is not pronounced. Grain refining of the melt using Al-5%Ti-1%B master alloy appreciably increases the tensile strength and ductility. Excess amounts of Fe and Mn decrease the tensile properties, particularly the ductility, by increasing the total amount of Fe-containing intermetallic phases. The addition of silver was found to improve the tensile properties and stimulate ageing. The addition of tin significantly decreases the tensile properties due to its melting during solution heat treatment. The addition of zirconium, which acts as grain refiner and forms Al3Zr dispersoids, improves the tensile properties of the Sn-containing alloys.

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References

  1. Smolej, A., Breskvar, B., Sokovic, M., Dragojevic, V., Slacek, E., Smolar, T., “Properties of Aluminum Free-Cutting Alloys with Tin, Part I,” Aluminium (Dusseldorf), vol. 78, pp 284–288 (2002)

    Google Scholar 

  2. Sircar, S., “X6030, A New Lead-Free Machining Alloy”, Materials Science Forum, vols. 217–222, pp 1795–1800 (1996)

    Article  Google Scholar 

  3. Gruzleski, J., Closset, B., The Treatment of Liquid Aluminum-Silicon Alloys, pp 25–55, American Foundrymen’s Society Inc., Des Plaines, IL (1990)

    Google Scholar 

  4. Hafiz, M. and Kobayashi, T., “Mechanical Properties of Modified and Non-modified Eutectic Al-Si Alloys,” Journal of Japan Institute of Light Metals, vol. 44, No. 1, pp 28–34 (1994)

    Article  Google Scholar 

  5. Fat-Halla, N., “Structural Modification of Al-Si Eutectic Alloy by Sr and its Effect on Tensile and Fracture Characteristics,” Journal of Materials Science, vol. 27, pp 2488–2490 (1989)

    Article  Google Scholar 

  6. Cibula, A., “The Grain Refinement of Al Alloy Castings by Addition of Ti and B,” Journal of the Institute of Metals, vol. 90, pp 1–16 (1951–52)

    Google Scholar 

  7. McCartney, D.G., “Grain Refining of Aluminum and its Alloys Using Inoculants,” International Materials Reviews, vol. 34, No. 5, pp 247–260 (1989)

    Article  Google Scholar 

  8. Guzowski, M.M., Sigworth, G.K., Sentner, D.A., “The Role of Boron in the Grain Refinement of Aluminum with Titanium,” Metallurgical & Materials Transactions A, vol. 18A, pp 603–620 (1987)

    Article  Google Scholar 

  9. Mohanty, P.S., Samuel, F.H., Gruzleski, J.E., “Studies on Addition of Inclusions to Molten Aluminum Using a Novel Technique,” Metallurgical & Materials Transactions B, vol. 26, No. 1, pp 103–109 (1995).

    Article  Google Scholar 

  10. Crepeau, P.N., “Effect of Iron in Al-Si Casting Alloys: A Critical Review,” AFS Transactions, vol. 103, pp 361–366 (1995)

    Google Scholar 

  11. Couture, A., “Iron in Aluminum Casting Alloys,” AFS International Cast Metals Journal, vol. 6, No. 6, pp 9–17 (1984)

    Google Scholar 

  12. Bonsack, W., “Discussion on the Effect of Minor Alloying Elements on Aluminum Casting Alloys,” ASTM Bulletin, pp 45–51(1942)

  13. ASM Handbook, Properties and Selection: Nonferrous Alloys and Special Purpose Materials, vol. 2, ASM International, Materials Park, OH (1990)

    Google Scholar 

  14. Gobrecht, J., “Ségrégation par Gravite du Fer, du Manganèse et du Chrome dans les Alliages Al-Si de Fonderie,” Fonderie, No. 367, pp 171–173 (1977)

  15. C. T. Rios, R. Caram, C. Bolfarini, W. J. Botta F and C. S. Kiminami, “Intermetallic Compounds in the Al-Si-Cu System”, ACTA Microscopia, vol. 12, No. 1, pp 77–81 (2003)

    Google Scholar 

  16. Samuel, F.H., Samuel, A.M., Doty, H.W., “Factors Controlling the Type and Morphology of Cu-Containing Phases in 319 Al Alloy,” AFS Transactions, vol. 30, pp 893–901 (1996)

    Google Scholar 

  17. Sigworth, G.K., “Controlling Tensile Strength in Aluminum Castings,” Private Communication, Alcoa Primary Metals, Rockdale, TX (2006)

    Google Scholar 

  18. Jorstad, J.L., Aluminum Casting Technology, 2nd ed., American Foundry Society, Des Plaines, IL, USA, 1993.

    Google Scholar 

  19. Fuoco, R., Correa, E.R., “Incipient Melting During Solution Heat Treatment of Al-Si-Mg and Al-Si-Cu-Mg Alloys,” AFS Transactions, vol. 110, pp 417–433 (2002)

    Google Scholar 

  20. Mondolfo, L.F., Aluminum Alloys: Structure and Properties, Butterworths, London-Boston (1976).

    Google Scholar 

  21. Reif, W., Yu, S., Dutkiewicz, J., Ciach, R., Krol, J., “Pre-Ageing of AlSiCuMg Alloys in Relation to Structure and Mechanical Properties,” Materials and Design, vol. 18, No. 4, pp 253–256 (1997)

    Article  Google Scholar 

  22. Mishra, R.K., Smith, G.W., Baxter, W.J., Sachdev, A.K., Franetovic, V., “The Sequence of Precipitation in 339 Aluminum Castings,” Journal of Materials Science, vol. 36, No. 2, pp 461–468 (2001)

    Article  Google Scholar 

  23. Hatch, J.E. (Ed.), Aluminum Properties and Physical Metallurgy, 1st ed., American Society for Metals, Metals Park, Ohio (1988)

    Google Scholar 

  24. Mahmudi, R., Sepehrband, P., Ghasemi, H.M., “Improved Properties of A319 Aluminum Casting Alloy Modified with Zr,” Materials Letters, vol. 60, pp 2606–2610 (2006)

    Article  Google Scholar 

  25. Sepehrband, P., Mahmudi, R., Khomamizadeh, F., “Effect of Zr Addition on the Ageing Behavior of A319 Aluminum Cast Alloy,” Scripta Materialia, vol. 52, No. 4, pp 253–257 (2005)

    Article  Google Scholar 

  26. Skrotzki, B., Shiflet, G.J., Starke, E.A., “On the Effect of Stress on Nucleation and Growth of Precipitates in an Al-Cu-Mg-Ag Alloy,” Metallurgical & Materials Transactions A, vol. 27A, pp 3431–3444 (1996)

    Article  Google Scholar 

  27. Muddle, B.C., Ringer, S.P., Polmear, I.J., “High Strength Microalloyed Aluminum Alloys,” in Advanced Materials’93 VI/Frontiers in Materials Science Engineering, pp 999–1023 (1994)

  28. Matsuda, K., Fukaya, K., Young, Z., Kawabata, T., Uetani, Y., Ikeno, S., “Effect of Copper, Silver and Gold on Tensile Behavior in Al-Mg-Si Alloy,” Materials Forum — Institute of Materials Engineering Australasia Ltd, vol. 28, pp 424–428 (2004)

    Google Scholar 

  29. Grebenkin, V.S., Sil’chenko, T.V., Gorshkov, A.A., Dzykovich, I.Y., “Effect of Magnesium on the Distribution of Tin and Lead in Al-Si Alloys,” Metallovedenie: Termicheskaya Obrabotka Metallov. (Metals Science & Heat Treatment), vol. 3, pp 50–54 (1972)

    Google Scholar 

  30. Silcock, J.M., Heal, T.J., Hardy, H.K., “The Structural Aging Characteristics of Ternary Al-Cu Alloys with Cd, In, or Sn,” Journal of the Institute of Metals, vol. 84, No. 1, pp 23–31 (1955)

    Google Scholar 

  31. Silcock, J.M., Flower, H.M., “Comments on a Comparison of early and Recent Work on the Effect of Trace Additions of Cd, In, or Sn on Nucleation and Growth of θ in Al-Cu Alloys,” Scripta Materialia, vol. 46, pp 389–94 (2002)

    Article  Google Scholar 

  32. Cizek, J., Melikhovo, O., Prochazka, I., Kuriplach, J., Stulikova, I., Vostry, P., “Annealing Process in Quenched Al-Sn Alloys: A Positron Annihilation Study,” Physical Review B, vol. 71, pp 1–13 (2005)

    Article  Google Scholar 

  33. Ringer, S.P., Hono, K., Sakurai, T., “The Effect of Trace Additions of Sn on Precipitation in Al-Cu Alloys: An Atom Probe Field Ion Microscopy Study,” Metallurgical and Materials Transactions A, vol. 26A, pp 2207–17 (1995)

    Article  Google Scholar 

  34. Kang, H.G., Kida, M., Miyahara, H., Ogi, K., “Age-Hardening Characteristics of Al-Si-Cu-Base Cast Alloys,” AFS Transactions, vol. 107, pp 507–515 (1999)

    Google Scholar 

  35. Lee, P.D., Sridhar, S., “Direct Observation of the Effect of Strontium on Porosity Formation During the Solidification of Aluminum-Silicon Alloys,” International Journal of Cast Metals Research, vol. 13, pp 185–198 (2000)

    Google Scholar 

  36. Shabestari, S.G., Grusleski, J.E., “Modification of Iron Containing Precipitates in AlSi12 Alloys with Strontium,” Giesserei-Praxis (Germany), vol. 17, pp 385–394 (1997)

    Google Scholar 

  37. Liao, H., Sun, G., “Mutual Poisoning Effect Between Sr and B in Al-Si Casting Alloys,” Scripta Materialia, vol. 48, pp 1035–1039 (2003)

    Article  Google Scholar 

  38. Liao, H., Sun, Y., Sun, G., “Effect of Al-5Ti-1B on the Microstructure of Near-eutectic Al-13.0%Si Alloys Modified with Sr,” Materials Science, vol. 37, pp 3489–3495 (2002)

    Article  Google Scholar 

  39. Czikel, J., Pfeiffer, W.D., Sabath, G., Steinhaufl, B., “Effects of Zinc, Iron and Manganese on the Properties of AlSi8Cu3 Type Alloys,” Aluminum, vol. 61, No. 12, pp 917–922 (1985)

    Google Scholar 

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Elgallad, E., Samuel, F., Samuel, A. et al. Development of New Al-Cu Based Alloys Aimed at Improving the Machinability of Automotive Castings. Inter Metalcast 3, 29–41 (2009). https://doi.org/10.1007/BF03355446

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