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Selective oxidation of alcohols to aldehydes by hydrogen peroxide using hexamolybdochromate(III) as catalyst

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Abstract

Anderson type hexamolybdochromate(III) was utilized as a catalyst for facile conversion of various aliphatic, benzylic and heterocyclic alcohols to corresponding aldehydes and ketones in good yields. The reaction was carried out in 50% aq. acetonitrile using hydrogen peroxide as the oxidant at 50 °C. The reaction was found to involve oxidation of the catalyst to its active Cr(V) intermediate by hydrogen peroxide.

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Authors and Affiliations

  1. Kinetics and Catalysis Laboratory, Department of Chemistry, Shivaji University, Kolhapur, 416004, Maharashtra State, India

    S. P. Mardur & G. S. Gokavi

Authors
  1. S. P. Mardur
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  2. G. S. Gokavi
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Correspondence to G. S. Gokavi.

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Mardur, S.P., Gokavi, G.S. Selective oxidation of alcohols to aldehydes by hydrogen peroxide using hexamolybdochromate(III) as catalyst. JICS 7, 441–446 (2010). https://doi.org/10.1007/BF03246030

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  • DOI: https://doi.org/10.1007/BF03246030

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