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Synthesis of Aldehydes and Ketones via Oxidation of Alcohols with Hydrogen Peroxide in Aqueous Acetonitrile in the Presence of Potassium Heptamolybdate Tetrahydrate Catalyst

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Abstract

Aldehydes and ketones are important intermediate products in C–C bond formation reactions, and carbonyl groups exist in many target molecules such as drugs and natural products. Therefore, in this study an ef­ficient catalytic procedure has been introduced for the synthesis of aldehydes and ketones via oxidation of alcohols with hydrogen peroxide in aqueous acetonitrile in the presence of potassium heptamolybdate tetrahydrate as catalyst. This catalyst impressively shortened the oxidation time compared to some previously reported methods. In addition, the catalyst could be easily reused in at least six successive reactions without significant loss of activity.

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ACKNOWLEDGMENTS

The authors are grateful to the Research Council of Payam Noor University for partial support of this work.

Funding

This study was financially supported by the Ministry of Science, Research, and Technology of Iran.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, 19395-3697, Tehran, Iran

    H. Hassani, M. Khosravi & M. Hakimi

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  1. H. Hassani
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  2. M. Khosravi
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  3. M. Hakimi
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Correspondence to H. Hassani.

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Hassani, H., Khosravi, M. & Hakimi, M. Synthesis of Aldehydes and Ketones via Oxidation of Alcohols with Hydrogen Peroxide in Aqueous Acetonitrile in the Presence of Potassium Heptamolybdate Tetrahydrate Catalyst. Russ J Org Chem 58, 1889–1894 (2022). https://doi.org/10.1134/S1070428022120181

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