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Kinetics of the olefine-bromine reaction

Part VI. Further consideration of the arrhenius parameters

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Summary

An analysis of the Arrhenius parameters for the addition reaction indicates that the reaction is a composite one and of the “slow” type. The influence of substituents on the energy of activation and on the frequency factor is discussed and the abnormal values of the latter are accounted for. A close correlation is also noticed between the two.

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Authors and Affiliations

  1. Department of Chemistry, Madras Christian College, Tambaram

    S. V. Anantakrishnan

  2. Annamalai University, India

    R. Venkatraman

Authors
  1. S. V. Anantakrishnan
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  2. R. Venkatraman
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Now at Lingaraj College, Belgaum

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Anantakrishnan, S.V., Venkatraman, R. Kinetics of the olefine-bromine reaction. Proc. Indian Acad. Sci. (Math. Sci.) 23, 320 (1946). https://doi.org/10.1007/BF03171057

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  • DOI: https://doi.org/10.1007/BF03171057

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