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The action of hexamethylene tetramine on phenols and the methyl esters of phenol carboxylic acids

Part IV. The synthesis and study of methyl-1-hydroxy-4-formyl 2-naphthoate and 2-acetyl-4-formyl-α-naphthol

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Summary

Methyl-1-hydroxy-4-formyl-2-naphthoate and 2-acetyl-4-formyl-α-naphthol have been synthesised by the action of hexamethylene tetramine in glacial acetic acid, on methyl-1-hydroxy-2-naphthoate and 2-acetyl-α-naphthol respectively.

Similar formylation of 4-acetyl-α-naphthol did not succeed.

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References

  1. Desai, Radha and Shah (Under publication).

  2. Lesser, A.402, 24.

  3. Robinson and Shah, J. 1934, 1497.

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Desai, R.D., Radha, K.S. & Shah, R.C. The action of hexamethylene tetramine on phenols and the methyl esters of phenol carboxylic acids. Proc. Indian Acad. Sci. (Math. Sci.) 23, 187 (1946). https://doi.org/10.1007/BF03170936

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  • DOI: https://doi.org/10.1007/BF03170936

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