Abstract
A study of multipulse sequences that can be used for the detection of HMX (N4(CH2)4(NO2)4) has been undertaken. On the basis of this study, a general method for experimentally optimizing multipulse sequences for the efficient detection of substances is proposed. The relaxation parameters and signal intensities for the nitrogen-14 spectral lines of a polycrystalline HMX sample were measured and the lines that are the most important for practical purposes were chosen.
Similar content being viewed by others
References
Hirschfeld T., Klainer S.M.: J. Mol. Struct.58, 63 (1980)
Garroway A.N., Buess M.L., Yesinowski J.P., Miller J.B. in: Substance Detection Systems (Harding G.L., Lanza R.C., Myers L.J., Young P.A., eds.), pp. 318–327. Bellingham, Wash.: SPIE—the International Society for Optical Engineering 1994 (Proceedings of the SPIE, vol. 2092)
Marino R.A., Klainer S.M.: J. Chem. Phys.67, 3388 (1977)
Harding J.C., Wade D.A., Marino R.A., Sauer E.G., Klainer S.M.: J. Magn. Reson.36, 21 (1979)
Bradford R., Clay C., Stick E.: Phys. Rev.84, 157 (1951)
Carr H.Y.: Phys. Rev.112, 1693 (1958)
Ernst R.R., Bodenhausen G., Wokaun A.: Principles of NMR in One and Two Dimensions. Oxford: Clarendon Press 1987.
Freeman R., Hill H.D.W.: J. Magn. Reson.4, 366 (1971)
Buess M.L., Garroway A.N., Miller J.B.: J. Magn. Reson.92, 348 (1991)
Rudakov T.N., Belyakov A.V., Mikhaltsevich V.T.: Meas. Sci. Technol.8, 444 (1997)
Rudakov T.N., Belyakov A.V.: J. Phys. D Appl. Phys.31, 1251 (1998)
Ostroff E.D., Waugh J.S.: Phys. Rev. Lett.16, 1097 (1966)
Landers R.A., Brill T.B., Marino R.A.: J. Phys. Chem.85, 2618 (1981)
Karpowicz R.J., Brill T.B.: J. Chem. Phys.97, 2100 (1983)
Rudakov T.N., Mikhaltsevich V.T.: Chem. Phys. Lett.363, 1 (2002)
Abe Y.: J. Phys. Soc. Jpn.23, 51 (1967)
Petersen G., Bray P.J.: J. Chem. Phys.64, 522 (1976)
Ernst R.R., Anderson W.A.: Rev. Sci. Instrum.37, 93 (1966)
Klainer S.M., Hirschfeld T.B., Marino R.A.: Fourier, Hadamard and Hilbert Transforms in Chemistry (Marshall A.G., ed.), pp. 147–181. New York: Plenum 1982.
Osokin D.Ya.: Zh. Eksp. Teor. Fiz.84, 118 (1983)
Kim S.S., Jayakody J.R.P., Marino R.A.: Z. Naturforsch. A47, 415 (1992)
Rudakov T.N., Mikhaltsevich V.T., Selchikhin O.P.: J. Phys. D Appl. Phys.30, 1377 (1997)
Yesinowski J.P., Buess M.L., Garroway A.N., Ziegeweid M., Pines A.: Anal. Chem.67, 2256 (1995)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rudakov, T.N., Hayes, P.A., Mikhaltsevitch, V.T. et al. Methods for optimizing the detection of HMX by nuclear quadrupole resonance. Appl. Magn. Reson. 25, 501–512 (2004). https://doi.org/10.1007/BF03166544
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF03166544