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Selective excitation of single lines of a multiplet for interpretation of spectra of complex multicomponent systems

  • Structure of Chemical Compounds. Spectroscopy
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Abstract

The article discusses the most important aspects of the selective RF excitation of multiplet single lines, an approach that makes it possible to simplify the spectra of complex multicomponent systems, to measure the spin–spin coupling constant, and to determine molecular structure. Semi-selective and selective methods of recording spectra are considered and theoretically substantiated based on the product operator formalism. The results are verified using quantum-mechanical calculations within the framework of the density matrix formalism. The paper demonstrates that the proposed new method leads to a significant simplification of two-dimensional nuclear magnetic resonance spectra. This makes it possible to study chemical processes and spin state exchange by observing the dynamic behavior of the multiplet structure of bound nuclei.

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References

  1. C. Bauer and R. Freeman, J. Magn. Reson. 61, 376 (1985).

    CAS  Google Scholar 

  2. A. Bax and R. Freeman, J. Am. Chem. Soc. 104, 1099 (1982).

    Article  CAS  Google Scholar 

  3. K. Wüthrich, NMR of Proteins and Nucleic Acids (Wiley-Interscience, New York, 1986).

    Google Scholar 

  4. S. Forsen, Rev. Part. Quim. 27, 15 (1985).

    Google Scholar 

  5. A. G. Redfield, S. D. Kuntz, and E. K. Ralph, J. Magn. Reson. 19, 114 (1975).

    CAS  Google Scholar 

  6. P. J. Hore, J. Magn. Reson. 55, 283 (1983).

    CAS  Google Scholar 

  7. D. L. Rabinstein, S. Fan, and T. T. Nakashma, J. Magn. Reson. 64, 541 (1985).

    Google Scholar 

  8. R. G. Bryant and T. M. Eads, J. Magn. Reson. 64, 312 (1985).

    CAS  Google Scholar 

  9. A. Bax, J. Magn. Reson. 65, 142 (1985).

    Google Scholar 

  10. U. Piantini and K. Ugurbil, J. Magn. Reson. 65, 207 (1985).

    Google Scholar 

  11. C. L. Dumoulin, J. Magn. Reson. 64, 38 (1985).

    CAS  Google Scholar 

  12. Yu. E. Chernysh and V. A. Volynkin, Russ. J. Phys. Chem. B 7, 371 (2013).

    Article  CAS  Google Scholar 

  13. R. Freeman, Spin Choreography. Basic Steps in High Resolution NMR (Oxford Univ. Press, Oxford, 1998).

    Google Scholar 

  14. R. Freeman, A Handbook of Nuclear Magnetic Resonance (Addison Wesley Longman, Oxford, 1988).

    Google Scholar 

  15. O. W. Sørensen, G. W. Eich, M. H. Levitt, G. Bodenhausen, and R. R. Ernst, Progr. Nucl. Magn. Reson. Spectrosc. 16, 163 (1983).

    Article  Google Scholar 

  16. Yu. E. Chernysh, G. S. Borodkin, B. S. Luk’yanov, et al., Selective NMR Fourier Spectroscopy and its Applications to Study of Molecular Dynamics Processes (Vyssh. Shcola, Sev.-Kavk. Tsentr, Rostov-on-Don, 2002) [in Russian].

    Google Scholar 

  17. F. J. M. van de Ven and C. W. Hilbers, J. Magn. Reson. 54, 512 (1983).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, 344006, Russia

    G. S. Borodkin & I. G. Borodkina

  2. Southern Federal University, Rostov-on-Don, 344006, Russia

    Yu. E. Chernysh & M. G. Morozov

  3. Kuban State University, Krasnodar, 350040, Russia

    V. T. Panyushkin & V. A. Volynkin

Authors
  1. G. S. Borodkin
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  2. I. G. Borodkina
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  3. Yu. E. Chernysh
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  4. M. G. Morozov
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  5. V. T. Panyushkin
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  6. V. A. Volynkin
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Corresponding author

Correspondence to Yu. E. Chernysh.

Additional information

Original Russian Text © G.S. Borodkin, I.G. Borodkina, Yu.E. Chernysh, M.G. Morozov, V.T. Panyushkin, V.A. Volynkin, 2017, published in Khimicheskaya Fizika, 2017, Vol. 36, No. 3, pp. 34–38.

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Borodkin, G.S., Borodkina, I.G., Chernysh, Y.E. et al. Selective excitation of single lines of a multiplet for interpretation of spectra of complex multicomponent systems. Russ. J. Phys. Chem. B 11, 228–232 (2017). https://doi.org/10.1134/S199079311702004X

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  • DOI: https://doi.org/10.1134/S199079311702004X

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