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CIDNP in photolysis of acetone solutions in plastic crystals of cyclohexane-d12

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Abstract

The emissive CIDNP was observed during photolysis of acetone solutions in solid cyclohexane-d12. The polarization is assumed to arise in contact triplet radical pairs as a result of their T_-S, conversion and their recombination.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Institutskaya 3, 630090, Novosibirsk, Russian Federation

    A. A. Obynochny, P. A. Purtov, A. G. Maryasov & Y. N. Molin

  2. Zavoisky Physical-Technical Institute, Kazan, Russian Federation

    K. M. Salikhov

  3. Institute of Physical-Organical Chemistry, Minsk, Byelorussia

    E. D. Skakovsky

Authors
  1. A. A. Obynochny
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  2. P. A. Purtov
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  3. A. G. Maryasov
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  4. Y. N. Molin
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  5. K. M. Salikhov
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  6. E. D. Skakovsky
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Obynochny, A.A., Purtov, P.A., Maryasov, A.G. et al. CIDNP in photolysis of acetone solutions in plastic crystals of cyclohexane-d12 . Appl. Magn. Reson. 9, 355–365 (1995). https://doi.org/10.1007/BF03161958

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  • DOI: https://doi.org/10.1007/BF03161958

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