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Force constants of diboranes

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Summary

Wilson’s group theoretical method has been employed in the investigation of force constants of two molecules B2 11H6 and B2 10D6 which possess the X2Y6 bridge structure. Symmetry co-ordinates which are orthonormalized and which satisfy the transformation properties have been constructed for the X2Y6 molecules possessing the bridge structure and belonging to the symmetry D2h . The elements of the F and the G matrices have been worked out. The secular equations have been solved to obtain a large number of force constants.

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References

  1. Wilson, E. B., Jr.J. Chem. Phys., 1939,7, 1047; 1941,9, 76.

    Article  Google Scholar 

  2. Hedberg, K. and Schomaker, V.J. Am. Chem. Soc., 1951,75, 1482.

    Article  Google Scholar 

  3. Bell, R. P. and Longuet-Higgins, H. C.Proc. Roy. Soc., 1945,183, 357.

    Article  Google Scholar 

  4. Anderson, T. F. and Burg, A. B.J. Chem. Phys., 1938,6, 586.

    Article  Google Scholar 

  5. Stitt, F.Ibid.,, 1941,9, 780.

    Article  Google Scholar 

  6. Lord, R. C. and Nielsen, E.Ibid.,, 1951,19, 1.

    Article  Google Scholar 

  7. Webb, A. N.,et al. Ibid.,, 1949,17, 1007.

    Article  Google Scholar 

  8. Anderson, W. E. and Barker, E. F.Ibid.,, 1950,18, 698.

    Article  Google Scholar 

  9. Beachell, H. C. and Levy, E. J.Ibid.,, 1955,23, 2168.

    Article  Google Scholar 

  10. Pondy, P. R. and BeachellIbid.,, 1956,25, 238.

    Article  Google Scholar 

  11. Bell, R. P.Proc. Roy. Soc., 1944,183 A, 328.

    Google Scholar 

  12. Badger, R. M.J. Chem. Phys., 1934,2, 128.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Annamalai University, Annamalainagar

    K. Venkateswarlu F.A.Sc. & P. Thirugnanasambandam

Authors
  1. K. Venkateswarlu F.A.Sc.
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  2. P. Thirugnanasambandam
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Venkateswarlu, K., Thirugnanasambandam, P. Force constants of diboranes. Proc. Indian Acad. Sci. 48, 344–354 (1958). https://doi.org/10.1007/BF03052919

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  • DOI: https://doi.org/10.1007/BF03052919

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