Abstract
The orange bands of FeO are excited in a low pressure arc in oxygen and photographed at dispersions of 0·8 and 0·5 Å/mm. respectively. Rotational analysis of five of the bands shows that they involve a1 Σ-1 Σ transition. The vibrational and rotational constants (in cm.−1) of the upper and lowerΣ states are found to be
In the low-pressure arc it is found that highly excited atomic lines appear very much reduced in intensity in contrast to spectra excited in an arc at atmospheric pressure.
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References
Rosen, B...Nature, 1945,156, 570.
Malet, L. and Rosen, B...Bull. Inst. Roy. Colon. Belg., 1945,14, 377.
Gatterer, A., Junkes, J. and Salpeter, E. W.Molecular Spectrum of Metallic Oxides, Specola Vaticana, 1957.
Dhumwad, R. K. and Bass, A. M.Applied Optics, 1963,2, 1335.
Delsemme, A. and Rosen, B.Bull. Soc. Roy. Sci., Liege, 1945,14, 70.
Herzberg, G...Spectra of Diatomic Molecules, D. Van Nostrand Company, Inc., Princeton, New Jersey, 1950.
Bass, A. M., Kuebler, N. A. and Nelson, L. S.J. Chem. Phys., 1964,40, 3121.
Harrison, G. R...M.I.T. Wavelength Tables, John Wiley and Sons, Inc., New York, 1939.
Crosswhite, H. M. ..John Hopkins Spectroscopic Report No. 13, 1958.
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Dhumwad, R.K., Narasimham, N.A. Rotational analysis of some of the bands of the orange system of FeO. Proc. Indian Acad. Sci. 64, 283–290 (1966). https://doi.org/10.1007/BF03047545
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DOI: https://doi.org/10.1007/BF03047545