Summary
Groundnut shell hemicellulose A1 has been shown to contain residues of D-xylose and D-glucuronic acid. The methylated polysaccharide gave on hydrolysis 2, 3, 4-tri-O-methyl-D-xylose, 2, 3-di-methyl-D-xylose and 2-O-(2, 3, 4-tri-O-methyl-D-glucuronosyl)-3-O-methyl-D-xylose in the molar ratio of 1: 30: 1. A structure is proposed for the hemicellulose which has a straight chain of ca. 30, 1: 4-linked β-D-xylopyranose residues with D-glucuronic acid existing as a side chain through the C2 position of one of the xylose residues.
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References
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Communicated by Prof. T. R. Seshadri,f.a.sc.
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Radhakrishnamurthy, B., Srinivasan, V.R. Studies on groundnut shells. Proc. Indian Acad. Sci. 46, 53–60 (1957). https://doi.org/10.1007/BF03045945
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DOI: https://doi.org/10.1007/BF03045945