Skip to main content
Log in

Microstructure and magnetic properties of rare earth Nd-Fe system alloys produced by containerless processing

  • Published:
Microgravity - Science and Technology Aims and scope Submit manuscript

Abstract

NdxFe100−1.5xB0.5x alloys (x=10, 11.8, and 14) were solidified from the undercooled melts by drop tube processing. The samples contained a large amount of the metastable phase with the composition near to their bulk composition in each alloy. The volume fraction of the metastable phase increased as the sample diameter decreased. The metastable phase was partially decomposed into very fine lamellar grains of the Nd2Fe14B and α-Fe or Nd2Fe14B and some Nd-rich phase by solid-state reaction in the samples with a diameter of 1200μm. The solidification behavior of the metastable phase was explained in terms of a hypothetic scheme of the pseudobinary Nd-Fe-B phase diagram

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Koon, N. C., Das, B. N., Rubinstein, M., Tyson, J.: Magnetic Properties of R2Fe14B Single Crystals. J. Appl. Phys. 57 p. 4091 (1985).

    Article  Google Scholar 

  2. Abache, C. Oesterreicher H.: Magnetic Properties of Compounds R2Fe14B. J. Appl. Phys. 57 p. 4112 (1985).

    Article  Google Scholar 

  3. Schneider, G., Hening, E.-T., Petzow, G. Stadelmaier H. H.: Phase Relations in the System Nd-Fe-B. Z. Metallkd. 77 p. 755 (1986).

    Google Scholar 

  4. Ozawa, S., Saito, T. Motegi, T.: Effects of Cooling Rate on Microstructures and Magnetic Properties of Nd-Fe-B Alloys. J. Alloys. Comp. 363 p. 263 (2004).

    Article  Google Scholar 

  5. Ozawa, S., Sato, H., Saito, T. Motegi, T.: Production of Nd-Fe-B Alloys by the Glass Slag Method. J. Appl. Phys. 91 p. 8831 (2002).

    Article  Google Scholar 

  6. Ozawa, S., Li, M., Sugiyama, S., Jimbo, I., Kuribayashi, K.: Direct Crystallization of the Nd2Fe14B peritectic Phase by Containerless Solidification in a Drop Tube. Mater. Trans. 44 p. 806 (2003) 806–810.

    Article  Google Scholar 

  7. Volkmann, T., Gao, J., Herlach, D. M.: Direct Crystallization of the Peritectic Nd2Fe14B1 Phase by Undercooling of Bulk Alloy Melts. Appl. Phys. Lett., 80 p. 1915 (2002).

    Article  Google Scholar 

  8. Gao, J., Volkmann, T., Herlach, D. M.: Undercooling-dependent Solidification Behavior of Levitated Nd14Fe79B7 Alloy Droplets, Acta Mater. 50 p. 3003 (2002).

    Article  Google Scholar 

  9. Gao, J., Volkmann, T., Roth, S., Löser, W., Herlach, D. M.: Phase Formation in Undercooled NdFeB Alloy Droplets. J. Magn. Magn. Mater. 234 p. 313(2001).

    Article  Google Scholar 

  10. Gao, J., Volkmann, T., Herlach, D. M.: Solidification of Levitated Nd-Fe-B Alloy Droplets at Significant Bulk Undercooling. J. Alloys. Comp. 350 p. 344 (2003).

    Article  Google Scholar 

  11. Ozawa S., Li M., Sugiyama S., Jimbo I., Hirosawa S., Kuribayashi K.: Microstructural Evolution and Magnetic Properties of the Nd-Fe-B Alloys Solidified from Undercooled Melt by Containerless Solidification. unpublished (2004).

  12. Ozawa S., Li M., Sugiyama S., Jimbo I., Hirosawa S., Kuribayashi K.: Magnetic Properties of New Metastable Phase from Undercooled Nd-Fe-B Melts. Journal of Applied Physics (in press).

  13. Ostwald, W.: Studien uber die Bildung und Umwandlung fester Korper. Z. Phys. Chem. 22 p. 289 (1897).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ozawa, S., Sugiyama, S., Li, M. et al. Microstructure and magnetic properties of rare earth Nd-Fe system alloys produced by containerless processing. Microgravity sci. Technol. 16, 89–93 (2005). https://doi.org/10.1007/BF02945954

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02945954

Keywords

Navigation