Abstract
The preparation of high quality ZnO/Si substrates for the growth of GaN blue light emitting materials is considered. ZnO thin films have been deposited on Si(100) and Si(111) substrates by conventional magnetron sputtering. Morphology, crystallinity andc-axis preferred orientation of ZnO thin films have been investigated by transmitting electron microscopy (TEM), X-ray diffraction (XRD) and X-ray rocking curve (XRC). It is proved that the ZnO thin films have perfect structure. The full-width-at-half-maximum (FWHM) of the ZnO(002) XRC of these films is about 1°, while the minimum is 0.353°. This result is better than the minimum FWHM (about 2°) reported by other research groups. Moreover, comparison and discussion are given on film structure of ZnO/Si(100) and ZnO/Si(111).
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References
Ueda, T., Huang, T. F., Spruytte, S. et al., Vapor phase epitaxy growth of GaN on pulsed laser deposited ZnO buffer layer, Journal of Crystal Growth, 1998, 187(3–4): 340.
Detchprohm, T., Hiramatsu, K., Amano, H. et al., Hydride vapor phase epitaxial growth of a high quality GaN film using a ZnO buffer layer, Applied Physics Letter, 1992, 61(22): 2688.
Qin, Z. X., Nagano, H., Sugure, Y. et al. High-resolution X-ray diffraction analysis of cubic GaN grown on (001) GaAs by RF-radical source molecular beam epitaxy, Journal of Crystal Growth, 1998, 189/190: 425.
Kim, Y., Kim, C. G., Lee, K. W. et al., Growth of hexagonal gallium nitride films on the (1110) surfaces of silicon with zinc oxide buffer layers Mat. Res. Soc. Symp. Proc., 1997, 449: 367.
Shirasawa, T., Honda, T., Koyama, F. et al., ZnO buffer formed on Si and sapphire substrates for GaN MOVPE, Mat. Res. Soc. Symp. Proc., 1997, 449: 373.
Guo, C. X., Fu, Z. X., Shi, C. S., Superlinear increase phenomenon of UV luminescence of ZnO film under cathodoluminescent excitation, Chinese Journal of Luminescence (in Chinese), 1998, 19(3): 239.
Hickernell, F. S., Zinc oxide films for acoustoelectric device applications, IEEE Trans. Sonics and Ultrasonics, 1985, SU-32(5): 621.
Fabula, Th, Wagner, H.-J., Schmidt, B. et al., Triple-beam resonant silicon force sensor based on piezoelectric thin films, Sensors and Actuators A 1994, 41/42: 375.
Gardeniers, J. G. E., Rittersma, Z. M., Burger, G. J., Preferred orientation and piezoelectricity in sputtered ZnO films, Journal of Applied Physics, 1998, 83(12): 7844.
Inukai, T., Matsuoka, M., Ono, K., Characteristics of zinc oxide thin films prepared by r.f. magnetron-mode electron cyclotron resonance sputtering, Thin Solid Films, 1995, 257: 22.
Pol, F. C. M., Blom, F. R., Popma, T. J. A., R. F. planar magnetron sputtered ZnO films I: structural properties, Thin Solid Films, 1991, 204: 349.
Fu, Z. X., Lin, B. X., Liao, G. H. et al., The effect of Zn buffer layer on growth and luminescence of ZnO films deposited on Si substrates, Journal of Crystal Growth, 1998, 193: 316.
Exarhos, G. J., Sharma, S. K., Influence of processing variables on the structure and properties of ZnO films, Thin Solid Films, 1995, 270: 27.
He, H. B., Fan, Z. X., Yao, Z. Y., Structure of ZnO thin films deposited on different substrates by sputtering, Journal of Functional Materials and Devices (in Chinese), 1999, 5(1): 66.
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He, H., Fan, Z., Yao, Z. et al. Sputtering of ZnO buffer layer on Si for GaN blue light emitting materials. Sci. China Ser. E-Technol. Sci. 43, 55–59 (2000). https://doi.org/10.1007/BF02917137
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DOI: https://doi.org/10.1007/BF02917137