Skip to main content
Log in

The suspension plasma spraying of bioceramics by induction plasma

  • Biomaterials
  • Research Summary
  • Published:
JOM Aims and scope Submit manuscript

Abstract

Suspension plasma spraying (SPS) is a single-step process for the preparation of thick coatings or for the production of powder using radio-frequency inductively coupled thermal plasma technology. SPS is based on a liquid suspension of very fine (<10 μm) or even ultrafine (,100 nm) powders axially fed into the radio-frequency plasma flame through an atomization probe. This article reports the results of the preparation by SPS of thick coatings and spherical powders of bioceramics, namely, hydroxyapatite. Characterization of the hydroxyapatite coatings and atomized powders are reported. Process variables are studied as a function of phase structure and crystallinity of the obtained hydroxyapatite material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R.H. Doremus, “Review Bioceramics,”Journal of Mat. Sci., 27 (1992), pp. 285–297.

    Article  CAS  Google Scholar 

  2. J.G.C. Wolke et al., “Studies on the Thermal Spraying of Apatite Bioceramics,”J. of Thermal Spray Tech., 1 (1992), pp. 75–82.

    Article  CAS  Google Scholar 

  3. C.C. Berndt et al., “Thermal Spraying for Bioceramic Applications,”Materials Forum, 14 (1990), pp. 161–173.

    CAS  Google Scholar 

  4. K.A. Thomas, “Hydroxyapatite Coatings,”Orthopaedics, 17, (3) (1994), pp. 267–278.

    CAS  Google Scholar 

  5. M.I. Boulos, “The Inductively Coupled R.F. (Radio Frequency) Plasma,”Pure and Applied Chemistry, 57 (9) (1985), pp. 1321–1352.

    Article  CAS  Google Scholar 

  6. M.I. Boulos, “RF Induction Plasma Spraying: State-of-the-art,”J. of Thermal Spray Tech., 1 (1) (1992) pp. 33–40.

    Article  Google Scholar 

  7. F. Gitzhofer, E. Bouyer, and M.I. Boulos, U.S. patent pending 8,296,674 (1994).

  8. E. Bouyer, F. Gitzhofer, and M.I. Boulos, “Suspension Plasma Spraying of Hydroxyapatite,”Proceedings of the 12th International Symposium of Plasma Chemistry, ed. J.V. Heberlein et al., vol. II (Minneapolis, MN: Organizing Committees of the 12th Int. Sym. on Plasma Chem., 1995), pp. 865–870.

  9. C. Simon, “Stabilisation of Aqueous Powder Suspensions in the Processing of Ceramics Materials,”Coagulation and Floculation, Theory and Applications, ed. Bohuslav Dobias (New York: Marcel Dekker, 1993), pp. 495–537.

    Google Scholar 

  10. Ph. Colomban, “Gel Technology in Ceramics, Glass-Ceramics and Ceramics-Ceramics Composites,”Ceramics International, 15 (1989), pp. 23–50.

    Article  Google Scholar 

  11. H. Tagai and H. Aoki, “Preparation of Synthetic Hydroxyapatite and Sintering of Apatite Ceramics,Mechanical Properties of Biomaterials, ed. G.W. Hastings and D.F. Williams (New York: John Wiley & Sons, 1987), pp. 213–220.

    Google Scholar 

  12. M.R. Christoffersen and J. Christoffersen, “Possible Mechanisms for the Growth of the Biomaterial, Calcium Hydroxyapatite Microcrystals,”Journal of Crystal Growth, 121 (1992), pp. 617–630.

    Article  CAS  Google Scholar 

  13. B.D. Cullity,Elements of X-Ray Diffraction, 2nd ed. (Addison-Wesley, 1978), p. 102.

  14. M. Jarcho, “Calcium Phosphate Ceramics as Hard Tissue Prosthetics,”Clin. Orthop. Relat. Res., 157 (1981), pp. 259–278.

    CAS  Google Scholar 

  15. A. Hasegawa et al., “Coating of Hydroxyapatite on Zirconia Utilizing a Radio-Frequency Thermal Plasma Process,”Journal of the Ceramic Society of Japan, 4 (4) (1992), pp. 377–381.

    Google Scholar 

  16. T. Kameyama et al., “Coating of Hydroxyapatite on Zirconia Utilizing a R.-F. Thermal Plasma Process,”Proceedings of Japanese Symposium on Plasma Chemistry, vol. 4 (Tokyo: Jap. Soc. for the Prom. of Sci., 1991), pp. 145–150.

  17. T. Kameyama et al., “Preparation of Oriented Hydroxyapatite Coatings on Zirconia Using a R.-F. Plasma Spraying Process”,Proceedings of the Japanese Symposium on Plasma Chemistry, vol. 5, (Tokyo: Jap. Soc. for the Prom. of Sci., 1992), pp. 257–262.

    Google Scholar 

  18. T. Kameyama et al., “Depth Profile of R.-F. Plasma Sprayed HydroxyaPatite Coatings on Zirconia Coatings,”Proceedings of the Japanese Symposium of Plasma Chemistry, vol. 6, (Tokyo: Jap. Soc. for the Prom. of Sci., 1993), pp. 1–6.

    Google Scholar 

  19. A.H. Lefebvre, “Atomizer Performance,”Atomization and Sprays (Hemisphere Publishing Corp., 1989), p. 241.

  20. M.I. Boulos, P. Fauchais, and E. Pfender,Thermal Plasmas, Fundamentals and Applications, vol. 1, (New York: Plenum Press, 1994), pp. 265–323.

    Google Scholar 

  21. P.V. Riboud, “Composition et Stabilité des Phases à Structure D’apatite Dans le Système CaO−P2O5-oxyde de Fer-H2O à Haute Fempérature,”Annales de Chimie, 8 (1973), pp. 381–390.

    CAS  Google Scholar 

  22. R. McPherson, N. Gane, and T.J. Bastow, “Structural Characterization of Plasma-sprayed Hydroxylapatite Coatings,”Journal of Mat. Sci. Materials in Medicine, 6 (1995), pp. 327–334.

    Article  CAS  Google Scholar 

  23. A.J. Ruys et al., “The Effects of Sintering Atmosphere on the Chemical Compatibility of HydroxyaPatite and Particulate Additives at 1200°C,”Journal of Mat. Sci.: Materials in Medicine, 6 (1995), pp. 297–301.

    Article  CAS  Google Scholar 

  24. J. Weng et al., “Further Studies on the Plasma-Sprayed Amorphous Phase in Hydroxyapatite Coatings and its Deamorphization”Biomaterials, 14 (8) (1993), pp. 578–582.

    Article  CAS  Google Scholar 

  25. C.M. Roome and C.D. Adam, “Crystallite Orientation and Anisotropic Strains in Thermally Sprayed Hydroxyapatite Coatings”,Biomaterials, 16 (1995), pp. 691–696.

    Article  CAS  Google Scholar 

  26. Y. Abe et al., “High-Strength Ca3(PO4)2 Glass Ceramics Prepared by Unidirectional Crystallization,”Journal of American Ceramic Society, 65 (1982), p. C-189.

    Article  CAS  Google Scholar 

  27. E. Boyer, F. Gitzhofer and M.I. Boulos, “Induction Plasma Spraying of Hydroxyapatite,”Proceedings of National Thermal Spray Conference, ed. C.C. Berndt and S. Sampath (Materials Park, OH: ASM, 1995), pp. 339–344.

    Google Scholar 

Download references

Authors

Additional information

E. Bouyer earned his M.Sc. in metallurgy from the University of Paris XI/Orsay in France in 1991. He is currently a Ph.D. candidate in chemical engineering at the Université de Sherbrooke.

F. Gitzhofer earned his Ph.D. in materials science from the University of Limoges in France in 1988. He is currently an associate professor and member of the Plasma Technology Research Centre in the Department of Chemical Engineering at the Université de Sherbrooke.

M.I. Boulos earned his Ph.D. in chemical engineering at the University of Waterloo in Canada in 1972. He is currently a full professor and director of the Plasma Technology Research Centre in the Department of Chemical Engineering at the Université de Sherbrooke.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bouyer, E., Gitzhofer, F. & Boulos, M.I. The suspension plasma spraying of bioceramics by induction plasma. JOM 49, 58–62 (1997). https://doi.org/10.1007/BF02915483

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02915483

Keywords

Navigation