Skip to main content
SpringerLink
Log in

Palladium-dihalide complexes with carbonyl donors

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

Palladium halides react with 4H-pyran-4-one (P) and 2,6-dimethyl-4H-pyran-4-one (DMP) to yield [Pd-(DMP)2X2] (X=Cl or Br), [Pd(P)2Cl2] and [Pd(P)Br2]n complexes which have been characterized by i.r. and proton n.m.r. spectroscopy. the thermal behaviour of the 4-pyrone adducts is correlated with that ofN,N-dimethylformamide analogues, [Pd(DMF)2Cl2] and [Pd(DMF)Br2]n, the ligand coordinating ability following the order: DMP>P>DMF. On the basis of i.r. spectra, the [Pd(L)2Cl2] (L-DMP or P) adducts should have the usualtrans configuration, whereas in both [Pd(P)Br2]n and [Pd(DMP)2Br2] a polymeric arrangement through bromine bridges should be present. The properties of the [Zn(P)2Cl2] and [Pt(DMP)2Cl2] complexes are also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Faraglia, F. Barbaro and S. Sitran,Transition Met. Chem.,15, 242 (1990).

    Article  CAS  Google Scholar 

  2. G. Faraglia and S. Sitran,Inorg. Chim. Acta,176, 67 (1990) and refs. therein.

    Article  CAS  Google Scholar 

  3. J. N. Macdonald, S. A. Mackay and J. K. Tyler,J. Chem. Soc., Faraday Trans.,77, 79 (1981).

    Article  CAS  Google Scholar 

  4. J. Staunton,Compr. Org. Chem.,4, 659 (1979).

    CAS  Google Scholar 

  5. J. M. Gioria and B. P. Susz,Helv. Chim. Acta,54, 246 (1971) and refs. therein.

    Article  Google Scholar 

  6. M. Goodgame and D. A. Jakubovic,Coord. Chem. Rev.,79, 97 (1987).

    Article  CAS  Google Scholar 

  7. V. Cherchi, G. Faraglia, L. Sindellari, S. Sitran and V. Scarcia,Inorg. Chim. Acta,155, 267 (1989) and refs. therein.

    Article  CAS  Google Scholar 

  8. G. Faraglia, Z. J. Guo and S. Sitran,Polyhedron,10, 351 (1991).

    Article  CAS  Google Scholar 

  9. G. Faraglia, D. Fregona, Z. J. Guo and S. Sitran,Thermochim. Acta,191, 95 (1991).

    Article  CAS  Google Scholar 

  10. G. Faraglia, L. Sindellari and S. Sitran,Thermochim. Acta,161, 63 (1990).

    Article  CAS  Google Scholar 

  11. A. R. Katritzky and R. A. Jones,Spectrochim. Acta,17, 64 (1961).

    Article  CAS  Google Scholar 

  12. P. Császár, A. Császár, Á. Somogyi, Z. Dinya, S. Holly, M. Gál and J. E. Boggs,Spectrochim. Acta,42A, 473 (1986).

    Google Scholar 

  13. G. Raudaschl, B. Lippert, J. D. Hoeschele, H. E. Howard-Lock, C. J. L. Lock and P. Pilon,Inorg. Chim. Acta,106, 141 (1985).

    Article  CAS  Google Scholar 

  14. D. B. Powell and A. Woolins,Spectrochim. Acta,41A, 1023 (1985).

    CAS  Google Scholar 

  15. G. Faraglia, R. Graziani, Z. J. Guo, U. Casellato and S. Sitran,Inorg. Chim. Acta, in press (1992).

Download references

Author information

Author notes

  1. Zijian Guo

    Present address: Department of Basic Courses, Agricultural University of Hebei, Baoding, P.R. China

Authors and Affiliations

  1. Dipartimento di Chimica Inorganica, Metallorganica ed Analitica dell'Università, via Loredan 4, 35131, Padova, Italy

    Dolores Fregona, Zijian Guo & Giuseppina Faraglia

  2. Istituto di Chimica e Tecnologia dei Radioelementi del C.N.R., corso Stati Uniti, 35020, Padova, Italy

    Sergio Sitran

Authors
  1. Dolores Fregona
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zijian Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Giuseppina Faraglia
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Sergio Sitran
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fregona, D., Guo, Z., Faraglia, G. et al. Palladium-dihalide complexes with carbonyl donors. Transition Met. Chem. 17, 242–246 (1992). https://doi.org/10.1007/BF02910847

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02910847

Keywords

Search

Navigation