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Structural-dynamic approach and path analysis of the intramolecular electron transfer in the bridged complexes [(NH3)5Ru-py-(C2H2) n -py-Ru(NH3)5]5+ withn = 0,1,2,3

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Abstract

The electron interaction transfer paths in the mixed-valence complexes[(NH3)5Ru-py-(C2H2)n-py-Ru(NH3)5]5+ are analyzed in the framework of perturbation theory. A structural-dynamic approach to treatment of the intramolecular electron transfer is proposed. This approach is based on the solution of the nonstationary Schrödinger equation in a basis of many-electron functions describing separate structural sites of the electron-transport chain RyII→pyridyl→ C2H2)n→pyridyl→RuIII.

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Authors and Affiliations

  1. St.-Petersburg State University, Russia

    O. V. Sizova, V. I. Baranovskii & A. I. Panin

Authors
  1. O. V. Sizova
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  2. V. I. Baranovskii
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  3. A. I. Panin
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Translated fromZhurnal Strukturnoi Khimii, Vol. 40, No. 2, pp. 211–227, March–April, 1999.

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Sizova, O.V., Baranovskii, V.I. & Panin, A.I. Structural-dynamic approach and path analysis of the intramolecular electron transfer in the bridged complexes [(NH3)5Ru-py-(C2H2) n -py-Ru(NH3)5]5+ withn = 0,1,2,3. J Struct Chem 40, 173–186 (1999). https://doi.org/10.1007/BF02903644

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  • DOI: https://doi.org/10.1007/BF02903644

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