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Action of space charge on aging and breakdown of polymers

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Chinese Science Bulletin

Abstract

The study on how space charges affect aging and breakdown of polymers becomes one of the most important domains. Most of the models are based on the injected charges increasing the local field to induce the breakdown of polymers and breaking the large molecule chains. These models ignore the effects of space charge on the microstructure of dielectric materials. In this review, with the calculation of the electromagnetic energy and the electromechanical energy around a trapped charge and with some new experimental results, it is proved that aging and breakdown in polymers are caused during the detrapping of the trapped charges. Aging and breakdown of the polymers are related to the release of the electromechanical energy around trapped charges.

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References

  1. Kao, K. C., Tu, D. M., Wu, L. H. et al., On the mechanism of tree initiation in polymers, IEEE Proc. Elec. Insul. Symp., 1982, 302.

  2. Dakin, T. M., Studniara, S. A., The voltage endurance of cast epoxy resins, IEEE Intern. Symp. on Electr. Insul., 1978, 216.

  3. Zhang, Y., Lewiner, J., Hanpton, N., Evidence of strong correlation between space charge buildup and breakdown in cable insulators under DC stress, IEEE Trans. Elect. Insul., 1996, 3(6): 778.

    Article  Google Scholar 

  4. Blaise, G., Sarjeant, W. J., Space charge in dielectrics energy storage and transfer dynamics from atomistic to macroscopic scale, IEEE Trans. Elect. Insul., 1998, 5(5): 779.

    Article  CAS  Google Scholar 

  5. Blaise, G., New approach to flashover in dielectrics based on a polarization energy relaxation mechanism, IEEE Trans. Elect. Insul., 1993, 28(4): 437.

    Article  CAS  Google Scholar 

  6. Fothergill, J. C., Filamentary electromechanical breakdown, IEEE Trans. Elect. Insul., 1991, 26(6): 1124.

    Article  Google Scholar 

  7. Gong, H., Le Gressus, C., Oh, K. H. et al., Charge trapping on different cuts of a single crystalline α SiO2, J. Appl. Phys. 1993, 74(3): 1944.

    Article  CAS  Google Scholar 

  8. Agnel, S., Toureille A., Le Gressus, C., Study of the aging of impregnated paper of high power capacitors using the thermal step method and the thermally stimulated currents, Conf. on Elect. Insul. and Diel. Phenom., IEEE Pub. 1996, 190.

  9. Jollet, F., Etude des modifications de la structure electronique des cxydes de siliciam (α-SiO2) et d’ytlrium (Y2O3) induities par des defauts de stractrue (non stoichiometrie, contraintes mècaniques, irradiation par des ions de grandes energies), Rapport CEA R-5517,1990.

  10. Lathamm, R. V., Diagnostic studies of prebreakdown electron pinholes and in HV vacuum insulation, Basic Con. Tech. Prac., 1995,66.

  11. Tanaka, T., Greenwood, A., Effects of charge injection and extraction on tree initiation in polyethylene, IEEE Trans. Pow. Appr. Sys.,PAS-95,1978, 1749.

  12. Bamji, S. S., Bulinski, A. T., Densley, R. J., Evidence of near-ultraviolet emission during electrical tree initiation in polyethylene, J. Appl. Phys., 1987, 62: 694.

    Article  Google Scholar 

  13. Tu, D. M., Kan, L., Application and the evidence of Kao’s theory in the breakdown of polymers, Journal of Xi’an Jiaotong University, 1989, 23(2): 17.

    Google Scholar 

  14. Nelson, J. K., Breakdown strength of solids in engineering dielectric, 1983, 11A: 445.

    Google Scholar 

  15. Bamji, S. S., Bulinske, A. T., Densley, R. J., Degration of polymeric insulation due to photoemission caused by high electric fields, IEEE Trans. Elect. Insul., 1989, 24: 91.

    Article  CAS  Google Scholar 

  16. Blaise, G., Le Gressus, C., Charge Trapping/detrapping processes and related breakdown phenomena in HV vacuum insulation, Basic Con. Tech. Prac., 1995: 330.

  17. Liu Ziyu, Liu Rongsheng, Wang Huiming, Space charges and initiation of electrical trees, Conf. Rec. 1985 Inter. Conf. Pro. Appl. Diel. Mater., 1985:23.

  18. Damamme, G., Le Gressus, C., De Reggi, A. S., Space charge characterization for the 21th century, IEEE Trans. Elect. Insul., 1997, 4(5): 558.

    Article  CAS  Google Scholar 

  19. Blaise, G., Le Gressus, C., Mise en Evidence d’un claquage des isolants associès à Dèstabilization d’une charge d’espace localisè, C. R. Acad. Sci., 1992, 314(11): 1017.

    CAS  Google Scholar 

  20. Dissado, L. A., Mazzanti, G., Montanari, G. C., The role of trapped space charge in the electrical aging of insulating materials, IEEE Trans. Elect. Insul., 1997, 4(5): 496.

    Article  CAS  Google Scholar 

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Li, J., Zhang, Y., Xia, Z. et al. Action of space charge on aging and breakdown of polymers. Chin.Sci.Bull. 46, 796–800 (2001). https://doi.org/10.1007/BF02900426

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  • DOI: https://doi.org/10.1007/BF02900426

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