Skip to main content
Log in

Laser induced photoemission electron and the generation of high Rydberg states of atoms and molecules

  • Bulletin
  • Published:
Chinese Science Bulletin

Abstract

Laser induced photoemission electron was produced by directing 532 nm and/or 355 nm onto stainless steel plate on a time of flight mass spectrometer. Multiple charged ions and high Rydberg states of atoms or molecules were successfully generated by impacts of the photoemission electrons. The high Rydberg states (n ∼ 40–100) thus produced were separated from ions, produced by direct electron impact ionization, by a 3 V DC electric field and then ionized by a delayed pulsed HV electric field in a ZEKE-PFI manner. Relationship between generation/property of high Rydberg states of atoms/molecules and experimental conditions could be investigated. Relationship between the electron accelerating voltage and high Rydberg states of Ar was described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Colby, S. M., Rielly, J. P., Photoemission electron impact ionization in time-of-flight mass spectrometry; an examination of experimental consequences,Int. J. Mass Spectrum: Ion Process, 1994, 131: 125.

    Article  CAS  Google Scholar 

  2. Dai, D. X., Bai, J. L., Yang, G. S.et al., Study of MPI spectroscopy-RETOF mass spectrometry in free jet beam,Science Progress of China, 1995, 5(2): 129.

    Google Scholar 

  3. Wiley, W. C., Mclaren, I. H., Time-of-flight mass spectrometer with improved resolution,Rev. Sci. Instrum., 1955, 26(12): 1150.

    Article  CAS  Google Scholar 

  4. Wang, L., Li, H. Y., Ma, C. S.et al., Application of the CAMAC system in TOF-MS measurement,Computers and Applied Chemistry (in Chinese), 1996, 13(2): 84.

    Google Scholar 

  5. Wang, L., Li, H. Y., Dai, D. X.et at., A novel method for producing multiple ionization of noble gas,Chinese Journal of Atomic and Molecular Physics (in Chinese), 1997, 14(2): 277.

    CAS  Google Scholar 

  6. Mueller-Dethlefs, K., Schlag, E. W., High-resolution zero kinetic energy (ZEKE) photoelectron spectroscopy of molecular system,Annu. Rev. Phys. Chem., 1991, 42: 109.

    CAS  Google Scholar 

  7. Zhu, L., Johnson, P., Mass analyzed threshold ionization spectroscopy,J. Chem. Phys., 1991, 94: 5769.

    Article  CAS  Google Scholar 

  8. Stebbings, R. E., Dunning, F. B.,Rydberg states of atoms and molecules. Cambridge: Cambridge University Press, 1983, 355.

    Google Scholar 

  9. Wang, L., Li, H. Y., Bai, J. L.et al., A novel method for the generation of high Rydberg states of atoms and molecules,Chem. Phys. Lett., 1998, 282: 204.

    Article  CAS  Google Scholar 

  10. Merkt, F., Molecules in High Rydberg states,Annu. Rev. Phy. Chem., 1997, 48: 669.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

About this article

Cite this article

Wang, L., Li, H., Bai, J. et al. Laser induced photoemission electron and the generation of high Rydberg states of atoms and molecules. Chin. Sci. Bull. 43, 1616–1620 (1998). https://doi.org/10.1007/BF02883405

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02883405

Keywords

Navigation