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[Na4(H2O)7][Fe(OH)6Mo6O18]: A new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center

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Abstract

The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (∼0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, [Na4(H2O)7][Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions.

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, China

    Chuande Wu, Xiang Lin, Rongmin Yu, Wenbin Yang, Canzhong Lu & Honghui Zhuang

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  1. Chuande Wu
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  2. Xiang Lin
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  3. Rongmin Yu
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  4. Wenbin Yang
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  5. Canzhong Lu
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  6. Honghui Zhuang
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Correspondence to Canzhong Lu.

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Wu, C., Lin, X., Yu, R. et al. [Na4(H2O)7][Fe(OH)6Mo6O18]: A new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center. Sc. China Ser. B-Chem. 44, 49–54 (2001). https://doi.org/10.1007/BF02879735

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  • DOI: https://doi.org/10.1007/BF02879735

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