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Dynamics of hexafluoroanions in complexes of tin and titanium with mixed alkaline metal cations

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Abstract

Dynamics of anions in LiMSnF6 and NaMTiF6 (M=K, Rb, Cs) are studied in the temperature range 170–400 (470) K. Types of internal mobility of anions are established, anion activation energies are estimated, and effects on the activation barrier are discussed.

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References

  1. V. Ya. Kavun, V. I. Sergienko, L. N. Ignatieva, et al.,Zh. Neorg. Khim.,35, No. 1, 174–179 (1990).

    CAS  Google Scholar 

  2. V. Ya. Kavun, V. I. Sergienko, and T. F. Antokhina,ibid., No. 7, 1820–1826.

  3. V. Ya. Kavun, V. I. Sergienko, and T. F. Antokhina,Zh. Strukt. Khim.,36, No. 4, 695–700 (1995).

    Google Scholar 

  4. S. P. Gabuda and A. G. Lundin,Internal Mobility in Solids [in Russian], Nauka, Novosibirsk (1986).

    Google Scholar 

  5. H. A. Resing and D. W. Davidson,Can. J. Phys.,54, No. 1, 295 (1976).

    CAS  Google Scholar 

  6. V. M. Buznik, V. Ya. Kavun, S. G. Bakhvalov, and E. M. Petrova, “Structure investigations of glasses of heavy metal fluorides. 2. General problems of NMR spectroscopy of topologically disordered glasses,” [in Russian], Preprint No. 719F, Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk (1992).

    Google Scholar 

  7. Yu. N. Moskvich, B. I. Cherkasov, A. A. Sukhovskii, and R. L. Davidovich, “Studies of ionic motions, conductivity, and superionic phase transitions in alkaline metal hexafluorozirconates, hafnates, and titanates,” Preprint No. 485F, Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk (1988).

    Google Scholar 

  8. T. F. Antokhina, N. N. Savchenko, L. N. Ignatieva, Et al.,Zh. Neorg. Khim.,42, No. 6 (1997).

    Google Scholar 

  9. S. P. Gabuda and S. V. Zemskov,Nuclear Magnetic Resonance in Complex Compounds [in Russian], Nauka, Novosibirsk (1976).

    Google Scholar 

  10. T. F. Antokhina, T. V. Lysun, V. I. Sergienko,Zh. Neorg. Khim.,36, No. 8, 2073–2076 (1991).

    CAS  Google Scholar 

  11. A. V. Gerasimenko, S. B. Ivanov, T. F. Antokhina, and V. I. Sergienko,Koordinats. Khim.,18, No. 2, 129–132 (1992).

    CAS  Google Scholar 

  12. A. V. Gerasimenko, S. B. Ivanov, T. F. Antokhina, and V. I. Sergienko,ibid., Nos. 10/11, 1139–1143.

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Authors
  1. V. Ya. Kavun
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Additional information

Institute of Chemistry, Far East Branch, Russian Academy of Sciences. Translated fromzhurnal Strukturnoi Khimii, Vol. 39, No. 1, pp. 61–65, January–February, 1998.

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Kavun, V.Y. Dynamics of hexafluoroanions in complexes of tin and titanium with mixed alkaline metal cations. J Struct Chem 39, 49–52 (1998). https://doi.org/10.1007/BF02873824

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  • DOI: https://doi.org/10.1007/BF02873824

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