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Effects of specific interactions on the anisotropy of crystal structure distortion of [Co(NH3)5NO2]Cl2 under hydrostatic pressure

  • Proceedings Of The 13th Seminar On Intermolecular Interactions And Conformations Of Molecules
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Abstract

Using some special experimental techniques for anisotropic refinement of the crystal structure of [Co(NH3)5NO2]Cl2 at high pressures gave results with an accuracy comparable to that obtained in normal conditions. The anisotropy of lattice compression under pressure is determined by specific interactions in crystals, in particular, by NH-Cl and NH-O hydrogen bonds. The anisotropy of compression at increased pressure is qualitatively distinct from that caused by lowered temperature for the same structure. This difference is also due to specific interactions (hydrogen bonds) in the structure.

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Authors
  1. E. V. Boldyreva
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  2. D. Yu. Naumov
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  3. H. Ahsbahs
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Additional information

Institute of Solid State Chemistry, Siberian Branch, Russian Academy of Sciences (Novosibirsk). Novosibirsk State University. Marburg University. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 3, pp. 433–447, May–June, 1998.

This work was supported by A. Humboldt Foundation.

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Boldyreva, E.V., Naumov, D.Y. & Ahsbahs, H. Effects of specific interactions on the anisotropy of crystal structure distortion of [Co(NH3)5NO2]Cl2 under hydrostatic pressure. J Struct Chem 39, 350–361 (1998). https://doi.org/10.1007/BF02873641

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