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Types of rotary crystal state of solid solutions of paraffins

  • Proceedings Of The 13th Seminar On Intermolecular Interactions And Conformations Of Molecules
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Abstract

Thermal deformations and polymorphous transformations of solid solutions of paraffins in C17–C19, C19–C21, C21–C23, C22–C24, and C23–C24 systems are investigated by thermal X-ray diffractometry using a temperature step of several tenths of a degree. It is examined how the length of a molecular chain of a homolog (n) and the difference in length (Δn) between the chains as well as the molecular composition of a solid solution affect these transitions, and the data are compared with those for the individual homologs of paraffins.

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St. Petersburg University. Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 3, pp. 380–394, May–June, 1998.

This work was supported by RFFR grant No. 97-05-65534 and ISSEP grants No. 156p and a97-2633.

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Filippova, I.V., Kotelnikova, E.N., Chazhengina, S.Y. et al. Types of rotary crystal state of solid solutions of paraffins. J Struct Chem 39, 307–317 (1998). https://doi.org/10.1007/BF02873636

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  • DOI: https://doi.org/10.1007/BF02873636

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