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Binary molybdates K4M2+(MoO4)3 (M2+=Mg, Mn, Co) and crystal structure of K4Mn(MoO4)3

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Binary molybdates K4M2+ (MoO4)3 (M2+=Mg, Mn, Co) isostructural to triclinic \ga-K4Zn(WO4)3 were synthesized, and optimal conditions for their spontaneous crystallization were found. It was established by XRPA and DTA that at 530°C the structure of the compound with cobalt undergoes a transition to the orthorhombic structure of K4Zn(MoO4)3. The structure of K4Mn(MoO4)3 was determined from single crystal diffraction data (a=7.613, b=9.955, c=10.156 Å,α=92.28,β=106.66,γ=105.58°, Z=2, space group\(P\bar 1\), R=0.030). In this compound, Mn has a higher coordination number (CN=5+1) than that of Zn inα-K4Zn(WO4)3 (CN=4+1). The main structural feature is pairs of MnO6 octahedra linked by the bridging MoO4 tetrahedra into ribbons stretching along the a axis. The structure is compared with related structures of binary molybdates and other members of the alluaudite family.

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Authors
  1. S. F. Solodovnikov
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  2. P. V. Klevtsov
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  3. Z. A. Solodovnikova
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  4. L. A. Glinskaya
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  5. R. F. Klevtsova
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 39, No. 2, pp. 282–291, March–April, 1998.

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Solodovnikov, S.F., Klevtsov, P.V., Solodovnikova, Z.A. et al. Binary molybdates K4M2+(MoO4)3 (M2+=Mg, Mn, Co) and crystal structure of K4Mn(MoO4)3 . J Struct Chem 39, 230–237 (1998). https://doi.org/10.1007/BF02873623

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  • DOI: https://doi.org/10.1007/BF02873623

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