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Quinone studies. Part III. Metal ion-catalysed oxidation of halophenols and halonaphthols by peroxidisulphate

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Astract

Oxidation of representative halophenols and halonaphthols by peroxidisulphate has been examined. The influence of metallic ions, viz. Cu2+, Fe3+, Ag+, on the above reaction has been studied. Cu2+ ion-catalyzed oxidation gives halo-1, 4-quinones in excellent yield. Potassium bis(biureto)cuprate(III) complex also oxidises halophenols to halo-1, 4-quinones.

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  1. Department of Organic Chemistry, Indian Institute of Science, 560012, Bangalore, India

    P Thirumalai Perumal & M Vivekananda Bhatt

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  1. P Thirumalai Perumal
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  2. M Vivekananda Bhatt
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Perumal, P.T., Bhatt, M.V. Quinone studies. Part III. Metal ion-catalysed oxidation of halophenols and halonaphthols by peroxidisulphate. Proc. Indian Acad. Sci. (Chem. Sci.) 101, 25–32 (1989). https://doi.org/10.1007/BF02869382

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  • DOI: https://doi.org/10.1007/BF02869382

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