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Phosphate coordination in copper(II) complexes

  • Inorganic and Analytical
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Abstract

The structural aspects of phosphate coordination in Cu(bipy)2 (H2PO4)2∼0·25 H3PO4 (1) and Cu(phen)2(H2PO4)2∼0·25 H3PO4 (2) (bipy=2,2′ bipyridyl; phen=1,10 phenanthroline) have been investigated byir, electronic andesr spectra. In both complexes bidentate coordination from H2PO −4 ion is suggested. The complexes have been assignedcis-distorted octahedral stereochemistry. It is interesting that the stereochemistry is essentially of a static nature in (1) while it is fluxional in (2).

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Authors and Affiliations

  1. Chemistry Division, Bhabha Atomic Research Centre, 400 085, Bombay, India

    M S Sastry, T kesavadas & G S Rao

  2. Radiochemistry Division, Bhabha Atomic Research Centre, 400 085, Bombay, India

    M D Sastry

Authors
  1. M S Sastry
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  2. T kesavadas
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  3. G S Rao
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  4. M D Sastry
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Sastry, M.S., kesavadas, T., Rao, G.S. et al. Phosphate coordination in copper(II) complexes. Proc. Indian Acad. Sci. (Chem. Sci.) 93, 843–848 (1984). https://doi.org/10.1007/BF02866346

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  • DOI: https://doi.org/10.1007/BF02866346

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