Abstract
The shapes and the fine structure of the x-ray LIII absorption discontinuity of rhenium have been studied in seven octahedral (K2ReCl6, K2ReBr6, (pyH)2ReCl6, (dipyH)2ReCl6, Re(dipy)Cl4, K3ReO2(CN)4 and ReO3) and three tetrahedral (KReO4, NH4ReO4 and NaReO4) compounds. The bond lengths in these compounds have been determined by applying Levy’s theory to the data on the fine structure associated with the edge beyond the molecular orbital region.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Aminoff B 1936Z. Kristallogr,A94 246
Bhat N V 1968, Ph. D. Thesis, University of Bombay.
Cotton F A and Wilkinson G 1967Advanced Inorganic Chemistry (Interscience Publishers, New York) p. 976
Kozlenkov A I 1961Izv. Akad. Nauk. SSSR. Ser. Fiz. 25 957
Levy R M 1965J. Chem. Phys. 43 1846
Levy R M, Van Wazer J R and SimpsonJ 1966Inorg. Chem. 5 332
Mande C and Chetal A R 1966Curr. Sci. 35 563
Mande C, Pendharkar A V and Chakravorti M C 1972Proc. Indian Acad. Sci. Sec. A 75 209
Meisel K 1932Z. Anorg. Allg. Chem. 207 121
Morrow J C 1960Acta Crystallogr. 13 443
Pendharkar A V 1972, Ph. D. Thesis, Nagpur University
Pendharkar A V and Mande C 1973Physica, Utrecht 66 204
Srivastava U C and Nigam H L 1972Curr. Sci. 41 18
Templeton D H and Dauben C H 1951J. Amer. Chem. Soc. 73 4492
Wyckoff R G W 1948Crystal Structures, Vol. 2 (Interscience Publishers, New York) Chap. VIII, Table on p. 13
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pendharkar, A.V., Mande, C. Determination of bond lengths in some compounds of rhenium from the x-ray LIII absorption discontinuity. Pramana - J. Phys. 1, 104–108 (1973). https://doi.org/10.1007/BF02847184
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02847184