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Isothermal compressibility and sound velocity of binary liquid systems: Application of hard sphere models

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Abstract

Sound velocity and density were measured in six binary liquid mixtures namely,n-heptane+toluene (I);n-heptane+n-hexane (II); toluene+n-hexane (III); cyclohexane+n-heptane (IV); cyclohexane+n-hexane (V), andn-decane+n-hexane (VI) at 298.15 K. The experimental isothermal compressibility has been evaluated from measured values of density and sound velocity. The isothermal compressibility of these mixtures has been calculated theoretically using different models for the hard sphere equation of state and also using Flory’s statistical theory. The computed values of isothermal compressibility were also compared with the experimentally evaluated values. A satisfactory agreement has been observed.

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References

  1. J D Pandey, B R Chaturvedi and N Pant,Acoust. Lett. 4, 92 (1980)

    Google Scholar 

  2. D K Majumdar and A R Purkait,Indian J. Pure Appl. Phys. 19 973 (1981)

    Google Scholar 

  3. N Pant, C V Chaturvedi and G D Chaturvedi,Z. Physik. Chem. (Leipzig)264, 513 (1983)

    Google Scholar 

  4. J D Pandey and U Gupta,Z. Physik. Chem. (Leipzig),268, 477 (1987)

    Google Scholar 

  5. J D Pandey and K Misra,Acoustic Lett. 6, 148 (1983)

    Google Scholar 

  6. B P Shukla and S N Dubey,Acoustic Lett. 9, 71 (1985)

    Google Scholar 

  7. J D Pandey, G P Dubey, B P Shukla and S N Dubey,Acustica,80, 92 (1994)

    Google Scholar 

  8. M Diaz Pena, G Tardagos, C Menduinar and R L Arenosa,J. Chem. Thermodyn. 11, 67 (1979)

    Article  Google Scholar 

  9. M B Ewing and K N Marsh,J. Chem. Thermodyn. 9, 371 (1977)

    Article  Google Scholar 

  10. P J Flory,J. Am. Chem. Soc. 87, 1833 (1965)

    Article  Google Scholar 

  11. P J Flory and A Abe,J. Am. Chem. Soc. 87, 1838 (1965)

    Article  Google Scholar 

  12. J D Pandey and R L Mishra,Acustica,32, 200 (1978)

    Google Scholar 

  13. J D Pandey and R L Mishra,Chem. Scr. 13, 63 (1978)

    Google Scholar 

  14. J D Pandey, N Pant, N Agrawal and Shikha,Acustica 68, 225 (1989)

    Google Scholar 

  15. J D Pandey, R K Shukla, A K Shukla and R D Rai,J. Chem. Thermodyn. 21, 125 (1989)

    Article  Google Scholar 

  16. CRC Handbook of Chem & Phys ed 60 (CRC Press, Boca Raton, Florida, 1979–80)

  17. J L Lebowitz, H L Frisch and E Helford,J. Chem. Phys. 34, 1037 (1961)

    Article  ADS  Google Scholar 

  18. E Thiel,J. Chem. Phys. 39, 474 (1963)

    Article  ADS  Google Scholar 

  19. M S Wertheim,Phys. Rev. Lett. 10, 321 (1963)

    Article  MATH  ADS  MathSciNet  Google Scholar 

  20. N F Carnahan and K E Starling,J. Chem. Phys. 51, 635 (1969)

    Article  ADS  Google Scholar 

  21. E A Guggenheim,Mol. Phys. 9, 43 (1965)

    Article  ADS  Google Scholar 

  22. H L Frisch,Adv. Chem. Phys. 6, 229 (1964)

    Article  Google Scholar 

  23. D Henderson,Mol. Phys. 30, 971 (1975)

    Article  Google Scholar 

  24. W G Hoover and F H Ree,J. Chem. Phys. 48, 3609 (1968)

    Article  ADS  Google Scholar 

  25. J G Mc-Gowan,Nature (London),210, 1255 (1966)

    Article  ADS  Google Scholar 

  26. N Auerbach,Experimentia 4, 473 (1948)

    Article  Google Scholar 

  27. M R Islam and S K Quadri,Acoust. Lett. 11, 237 (1988)

    Google Scholar 

  28. G A Mansoori, N F Carnathan, K E Starling and T W Leland,J. Chem. Phys. 54, 1523 (1971)

    Article  ADS  Google Scholar 

  29. F Kohler, R Kohler and P Svedja,Fluid Phase Equilibria,27, 189 (1986)

    Article  Google Scholar 

Download references

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Pandey, J.D., Jain, P. & Vyas, V. Isothermal compressibility and sound velocity of binary liquid systems: Application of hard sphere models. Pramana - J. Phys. 43, 361–372 (1994). https://doi.org/10.1007/BF02846703

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  • DOI: https://doi.org/10.1007/BF02846703

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