Abstract
The ligand 1,2-di(o-aminophenylthio)ethane (abbreviated as H2DAPTE) has been allowed to react with various metal salts and the complexes isolated and characterised. In these complexes, H2 DAPTE behaves as a neutral quadridentate and also as a dibasic quadridentate ligand after losing two protons from the amine functions. Two complexes of this ligand, reported earlier, have been condensed with acetone to form macrocyclic complexes of TDDH where TDDH is 13, 13, 15-trimethy1-2,5-dithia-12, 16-diazatricyclo-[15,3,0,0,6,11]-docosa-1(17), 6(11), 7,9,15,18,20-heptene.
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Mukherjee, G., Pal, S., Poddar, S.N. et al. Complexes of N, S donor ligands. CoII, CoIII, MnIII, FeIII and PdII complexes of 1, 2-di(o-aminophenylthio)ethane: Synthesis, characterisation and reactions. Proc. Indian Acad. Sci. (Chem. Sci.) 105, 1–9 (1993). https://doi.org/10.1007/BF02841344
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DOI: https://doi.org/10.1007/BF02841344