Abstract
Ru(III), Rh(III), Pt(IV) and Ir(III) complexes of 2-furfural thiosemicarbazone as ligand have been synthesised. These complexes have the composition [M(ligand)2X2]X (M = Ru(III) Rh(III) and Ir(III) X = Cl and Br) and [Pt(ligand)2 X2] X2 (X = Cl, Br and 1/2SO4). The deprotonated ligand forms the complexes of the formulae M(ligand-H)3 and Pt(ligand-H)3Cl. All these complexes have been characterized by elemental analysis, magnetic measurements, electronic and infrared spectral studies. All the complexes are six-coordinate octahedral.
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References
Ali M A and Livingstone S E 1974Coord. Chem. Rev. 13 101
Bertelli E, Preti C and Tosi G 1975J. Inorg. Nucl. Chem. 37 1421
Burns G R 1968Inorg. Chem. 7 277
Campbell M J M, Grzeskowiak R and Thomas R 1976Spectrochim. Acta. A32 556
Chandra S 1983Synth. React. Inorg. Met.-Org. Chem. 13 89
Figgis B N and Lewis J 1960Modern coordination chemistry (eds) J Lewis and R G Wilkins (New York: Interscience Publishers) p. 448
Jensen K A 1934Z. Anorg. Allg. Chem. 221 6
Jensen K A 1936Z. Anorg. Allg. Chem. 229 265
Jørgenson C K 1962Prog. Inorg. Chem. 4 73
Jørgenson C K 1964Absorption spectra and chemical bonding in complexes (London: Pergamon)
Lever A B P 1968Inorganic electronic spectroscopy (Amsterdam: Elsevier)
Livingstone S E, Mayfield J H and Moore D S 1975Aust. J. Chem. 28 2531
Mahadevappa D S, Gowde B T and Murthy A S A 1976Indian J. Chem. A14 985
Marcotrigiano G, Pellacani G C, Preti C and Tosi G 1975Bull. Chem. Soc. Jpn. 48 1018
Mashima M 1964Bull. Chem. Soc. Jpn. 37 974
Mukkanti K, Pandeya K B and Singh R P 1982Indian J. Chem. A21 641
Mukkanti K, Pandeya K B and Singh R P 1986Synth. React. Inorg. Met.-Org. Chem. 16 229
Preti C and Tosi G 1977J. Coord. Chem. 7 35
Rana V B, Sahni S K, Swami M P, Jain P C and Srivastava A K 1976J. Inorg. Nucl. Chem. 38 176
Sah P T and Daniels T C 1950Rec. Trav. Chim. 69 1545
Sahni S K, Jain P and Rana V B 1978Indian J. Chem. A16 699
Sahni S K, Jain P and Rana V B 1979Indian J. Chem. A18 161
Sengupta S K, Sahni S K and Kapoor R N 1980Synth. React. Inorg. Met.-Org. Chem.,10 269
Wiles D M and Suprunchuk T 1969Can. J. Chem. 47 1087
Yamaguchi A, Penland R B, Mizushima S, Lane T J, Curran C and Quagliane J U 1958J. Am. Chem. Soc. 80 527
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Mukkanti, K., Singh, R.P. Synthesis and characterization of Ru(III), Rh(III), Pt(IV) and Ir(III) thiosemicarbazone complexes. Proc. Indian Acad. Sci. (Chem. Sci.) 100, 21–26 (1988). https://doi.org/10.1007/BF02839523
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DOI: https://doi.org/10.1007/BF02839523