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Synthesis and structure of ruthenium complexes [Ph3PCH2C6H4F-4]2[RuCl6] and [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]

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Abstract

The reaction of (4-fluorobenzyl)triphenylphosphonium chloride with ruthenium(iii) chloride hydrate in the presence of hydrochloric acid in dimethyl sulfoxide affords the complex [Ph3PCH2C6H4F-4]2[RuCl6]. In the absence of hydrochloric acid, the reaction gives the complex [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]. The structures of the complexes were studied by 1H, 19F, and 31P NMR spectroscopy and X-ray diffraction.

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Authors and Affiliations

  1. South Ural State University, 76 prosp. im. V. I. Lenina, 454080, Chelyabinsk, Russian Federation

    V. V. Sharutin, O. K. Sharutina & V. S. Senchurin

  2. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620990, Ekaterinburg, Russian Federation

    M. I. Kodess

Authors
  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. S. Senchurin
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  4. M. I. Kodess
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Correspondence to V. V. Sharutin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 0946—0950, June, 2017.

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Sharutin, V.V., Sharutina, O.K., Senchurin, V.S. et al. Synthesis and structure of ruthenium complexes [Ph3PCH2C6H4F-4]2[RuCl6] and [Ph3PCH2C6H4F-4][trans-RuCl4(dmso-S)2]. Russ Chem Bull 66, 946–950 (2017). https://doi.org/10.1007/s11172-017-1836-2

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  • DOI: https://doi.org/10.1007/s11172-017-1836-2

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