Abstract
Al−Cr-pillared montmorillonite was synthesized by using bentonite and Al−Cr pillaring solutions as starting materials. The basal spacing and specific surface areas of the materials were significantly increased relative to those of untreated clays. When the Al/Cr molar ratio (R) was 0.10, the d(001) value and specific surface area of pillared montmorillonite were 1.9194 nm and 165.7 m2g−1, respectively. Thermal stability of the materials was determined using calcined tests and X-ray diffraction (XRD) analysis. The materials formed at different R(0.05;0.10;0.15;0.25) exhibit a high thermal stability at 300°C, especially at initial R=0.10, the basal interlayer spacing of materials is stabilized at 1.7313 nm after calcined at 500°C for 2 h. Adsorption behavior of the materials was studied by adsorption experiments. The results show that the Al−Cr-pillared montmorillonites exhibit much stronger adsorption capacity on Cr6+ in aqueous solution than untreated clays do.
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CAO Ming-li: Born in 1965
Supported by Specialized Research Fund for the Doctoral Program of Higher Education (No. 20020497005) and for University Key Teacher by the Ministry of Education, China
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Ming-li, C., Shi-zhen, L. & Yong-fu, Y. Synthesis and characterization of Al−Cr-pillared montmorillonite with high thermal stability and adsorption capacity. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 19, 51–53 (2004). https://doi.org/10.1007/BF02838363
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DOI: https://doi.org/10.1007/BF02838363