Skip to main content
SpringerLink
Log in

Physicochemical basis of uniform, pseudoselective, and selective dissolution of homogeneous alloys

  • Published:
Protection of Metals Aims and scope Submit manuscript

Abstract

Presently accepted mechanisms of anodic dissolution of homogeneous metal alloys—uniform dissolution, pseudoselective dissolution, and selective dissolution with phase conversion in the surface layer— have a unified physicochemical basis. The relative contribution of one or another mechanism depends, in particular, on the probability of the formation of new-phase nuclei on the surface of dissolving alloy and also on the kinetic parameters of ionization and back deposition of the noble component ions. The uniform dissolution tends to give way to the selective one, and the mechanism of pseudoselective dissolution can serve as the transition, connecting link.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pickering, H.W. and Wagner C.,J. Electrochem. Soc., 1967, vol. 114, no. 7, p. 698.

    Article  CAS  Google Scholar 

  2. Losev, V.V., Pchel’nikov, A.P. and Marshakov, A.I.,Elektrokhimiya, 1979, vol. 15, no. 6 p. 837.

    CAS  Google Scholar 

  3. Marshakov, A.I., Pchel’nikov, A.P. and Losev, V.V.,ibid., 1982, vol. 18, no. 4, p. 537.

    CAS  Google Scholar 

  4. Polunin, A. V., Pozdnyakova, I.A., Pchel’nikov, A.P.,et al., ibid., no. 6, p. 792.

    CAS  Google Scholar 

  5. Marshakov, A.I., Pchel’nikov, A.P., and Losev, V.V.,ibid., 1983, vol. 19, no. 3, p. 356.

    CAS  Google Scholar 

  6. Pchel’nikov, A.P., Sitnikov, A.D., and Losev, V.V.,Zashch. Met., 1977, vol. 13, no. 3, p. 288.

    CAS  Google Scholar 

  7. Sitnikov, A.D., Pchel’nikov, A.P., Marshakov, I.K.,et al., ibid., 1978, vol. 14, no. 3, p. 258; 1979, vol. 15, no. 1, p. 34.

    CAS  Google Scholar 

  8. Pchel’nikov, A.P., Sitnikov, A.D., Polunin, A.V.,et al., Elektrokhimiya, 1980, vol. 16, no. 4, p. 477.

    CAS  Google Scholar 

  9. Marshakov, I.K., Ugai, Ya.A., Vigdorovich, V.I.,et al., ibid., 1966, vol. 2, no. 2, p. 254.

    CAS  Google Scholar 

  10. Marshakov, I.K. and Vyazovikina, N.V.,Zashch. Met., 1978, vol. 14, no. 4, p. 410.

    CAS  Google Scholar 

  11. Pchel’nikov, A.P., Sokol’skaya, I.L., Zakhar’in, D.S.,et al., Elektrokhimiya, 1980, vol. 16, no. 10, p. 1479.

    CAS  Google Scholar 

  12. Pchelnikov, A.P., Sitnikov, A.D., Marshakov, I.K.,et al., Electrochim. Acta, 1981, vol. 26, no. 5, p. 591.

    Article  CAS  Google Scholar 

  13. Vyazovikina N.V., Marshakov, I.K., and Tutukina, N.M.,Elektrokhimiya, 1981, vol. 17, no. 6, p. 838.

    CAS  Google Scholar 

  14. Polunin, A.V., Pchel’nikov, A.P., Losev, V.V.,et al., ibid., no. 6, p. 838.

    Google Scholar 

  15. Zartsyn, I.D., Protasova, I.V., Shugurov A.E.,et al., Zashch. Met., 1996, vol. 32, no. 5, p. 468.

    Google Scholar 

  16. Alekperov, S.D., Pchel’nikov, A.P., Chervyakov, V.N.,et al., ibid., 1989, vol. 25, no. 6, p. 883.

    CAS  Google Scholar 

  17. Zartsyn, I.D., Kondrashin, V.Yu., and Marshakov, I.K.,ibid., 1986, vol. 22, no. 4, p. 528;Dokl. Akad. Nauk SSSR, 1987, vol. 295, no. 2, p. 405.

    CAS  Google Scholar 

  18. Marshakov, I.K., Vyazovikina, N.V., and Derevenskikh, L. V.,Zashch. Met., 1979, vol. 15, no. 3, p. 337.

    CAS  Google Scholar 

  19. Zartsyn, I.D., Vvedenskii, A.V. and Marshakov, I.K.,Elektrokhimiya, 1991, vol. 27, no. 1, p. 3.

    CAS  Google Scholar 

  20. Idem, ibid. , 1994, vol. 30, no. 4, p. 544.

    Google Scholar 

  21. Pickering, H.W.,Corros. Sci., 1983, vol. 23, no. 10, p. 1107.

    Article  CAS  Google Scholar 

  22. Frenkel’, Ya.I.,Sobranie izbrannykh trudov (Selected Works), vol. 2:Nauchnye stat’i (Scientific Papers), Moscow: Akad. Nauk SSSR, 1958, p. 333.

    Google Scholar 

  23. Folmer, M.,Kinetika obrazovaniya novoi fazy (The Kinetics of Formation of a New Phase), Moscow: Nauka, 1986, p. 93.

    Google Scholar 

  24. Landau, L.D. and Lifshits, E.M.,Statisticheskaya fizika (Statistical Physics), Moscow: Nauka, 1964, p. 554.

    Google Scholar 

  25. Kabanov, B.N.,Elektrokhimiya metallov i adsorbtsiya (Electrochemistry of Metals and Adsorption), Moscow: Nauka, 1966, p. 4.

    Google Scholar 

  26. Kondrashin, V.Yu. and Marshakov, I.K.,Zashch. Met., 1990, vol. 26, no. 3, p. 355.

    CAS  Google Scholar 

  27. Kondrashin, V.Yu.,ibid., 1992, vol. 28, no. 1, p. 48.

    CAS  Google Scholar 

  28. Kondrashin, V.Yu., Bokov, G.A., and Marshakov, I.K.,ibid., 1994 vol. 30, no. 3, p. 229.

    CAS  Google Scholar 

  29. Kondrashin, V.Yu., Ovchinnikova, E.A., and Marshakov, I.K.,ibid., 1997, vol. 33, no. 3, p. 259.

    Google Scholar 

  30. Tutukina, N.M., Kondrashin, V.Yu., and Marshakov, I.K.,Elektrokhimiya, 1988, vol. 24, no. 6, p. 920.

    CAS  Google Scholar 

  31. Kondrashin, V.Yu. and Marshakov, I.K.,ibid., 1997, vol. 33, no. 9, p. 1017.

    Google Scholar 

  32. Vetter, K.,Elektrochemische Kinetik, Berlin: Springer, 1961.

    Google Scholar 

  33. Kondrashin, V.Yu.,Elektrokhimiya, 1998, vol. 34, no. 2, p. 160.

    Google Scholar 

  34. Novakovskii, V.M., Iksanov, B.A., Tolstaya, M.A.,et al., Zashch. Met., 1984, vol. 20, no. 4, p. 565.

    CAS  Google Scholar 

  35. Polunin, A.V., Pchelnikov, A.P., Losev, V.V.,et al., Electrochim. Acta, 1982, vol. 27, no. 4, p. 467.

    Article  CAS  Google Scholar 

  36. Vyazovikina, N.V., Gorkina, I.K., and Marshakov, I.K.,Elektrokhimiya, 1982, vol. 18, no. 10, p. 1391.

    CAS  Google Scholar 

  37. Kolotyrkin, Ya.M., Knyazheva, V.M., Plaskeev, A.V.,et al., Dokl. Akad. Nauk SSSR, 1976, vol. 226, no. 2, p. 382.

    CAS  Google Scholar 

  38. Chernova, G.P., Tomashov, N.D., and Serdyuk, T.M.,Zashch. Met., 1987, vol. 23, no. 2, p. 272.

    CAS  Google Scholar 

  39. Vyazovikina N.V., Yagupol’skaya, L.N., Ivashchenko, Yu.N.,et al., ibid., 1988, vol. 24 no. 1, p. 60.

    CAS  Google Scholar 

  40. Bokov, G.A., Pchel’nikov, A.P., Marshakov, I.K., and Losev, V.V.,Elektrokhimiya, 1985, vol. 21, no. 7, p. 991.

    CAS  Google Scholar 

  41. Zartsyn, I.D., Kondrashin, V.Yu., and Marshakov, I.K.,Zashch. Met., 1989, vol. 25, no. 1, p. 8.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Voronezh State University, Universitetskaya pl. 1, 394693, Voronezh, Russia

    V. Yu. Kondrashin & I. K. Marshakov

Authors
  1. V. Yu. Kondrashin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. K. Marshakov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kondrashin, V.Y., Marshakov, I.K. Physicochemical basis of uniform, pseudoselective, and selective dissolution of homogeneous alloys. Prot Met 36, 438–444 (2000). https://doi.org/10.1007/BF02764088

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02764088

Keywords

Search

Navigation