Skip to main content
SpringerLink
Log in

Synthesis and properties of Pb1-xVxO2-x(OH)x, solid solutions

  • Published:
Inorganic Materials Aims and scope

Abstract

Pb1-xVxO2-x(OH)x (0 <x ≤0.30) solid solutions with the rutile structure were prepared by reacting humid β-PbO2 + V2O5 mixtures at temperatures from 200 to 250°C. At higher vanadium contents, lead hexavanadate, PbV6O16, was formed, as inferred from IR spectroscopy data. The structural and electrical properties of the solid solutions were studied, and the valence state of the constituent ions was determined. All of the vanadium has a valence of 4+ forx ≤ 0.06 and 5+ forx > 0.15. The lead ions are in the oxidation states 4+ and 2+ over the entire range of solid solution

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Volkov, V.L. and Buldakova, L.Yu., Oxygen Chemisorption on the Surface of VO2.5-δ-SnO2(TiO2) Compounds,Elektrokhimiya, 1994, vol. 30, no. 7, pp. 892–896.

    Google Scholar 

  2. Boher, P., Garnier, P., and Gavarri, J.R., Mise en évidence et localisation des protons dans les bioxydes de plomb PbO2 α et β chimiques et éléctrochimiques,J. Solid State Chem., 1984, vol. 52, no. 2, pp. 146–155.

    Article  CAS  Google Scholar 

  3. Karyakin, Yu.V. and Angelov, I.I.,Chistye khimicheskie reaktivy (Pure Reagents), Moscow: Khimiya, 1974, p. 320.

    Google Scholar 

  4. Rietveld, H.M., A Profile Refinement Method for Nuclear and Magnetic Structures,J. Appl. Crystallogr., 1969, vol. 2, no. 1, pp. 65–71.

    Article  CAS  Google Scholar 

  5. Howard, S.A.,A Program for Rietveld Analysis of X-ray and Neutron Powder Diffraction Patterns: DBW4.1, Univ. of Missouri-Rolls, 1989.

  6. Smith, G.S. and Snyder, R.L.,F N : A Criterion for Rating Powder Diffraction Patterns and Evaluating the Reliability of Powder Pattern Indexing,J. Appl. Crystallogr., 1979, vol. 12, no. 2, pp. 60–65.

    Article  CAS  Google Scholar 

  7. D’Antonio, P. and Santoro, A., Powder Neutron Diffraction Study of Chemically Prepared Beta-Lead Dioxide,Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1980, vol. 36, no. 10, pp. 2394–2398.

    Article  Google Scholar 

  8. Sovremennaya kristallografiya (Modern Crystallography), Vainshtein, B.K., Chernov, A.A., and Shuvalov, L.A., Eds., Moscow: Nauka, 1979, vol. 2, p. 75.

    Google Scholar 

  9. Kim, K.S., O’Leary, T.J., and Winograd, N., X-ray Photoelectron Spectra of Lead Oxides,Anal. Chem., 1973, vol. 45, no. 13, pp. 2214–2218.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, Pervomaiskaya ul. 91, 620219, Yekaterinburg, Russia

    V. L. Volkov, G. S. Zakharova, M. V. Kuznetsov, V. G. Zubkov, I. F. Berger & A. P. Tyutyunnik

Authors
  1. V. L. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. S. Zakharova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Zubkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. F. Berger
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. P. Tyutyunnik
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Volkov, V.L., Zakharova, G.S., Kuznetsov, M.V. et al. Synthesis and properties of Pb1-xVxO2-x(OH)x, solid solutions. Inorg Mater 36, 49–53 (2000). https://doi.org/10.1007/BF02758379

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02758379

Keywords

Search

Navigation