Abstract
Coating properties and performance can be tailor-designed by proper control of nano structure andprocess conditions. This paper presents two examples: first, the synthesis and optimization of 1 nm thick nitrogenated carbon (CNx) nano-layers as protective overcoats in extremely highdensity harddisksystems, and, second, the development of multilayer coatings for wear protection at elevated temperatures. Synthesis of these coatings was done by magnetron sputtering. These studies demonstrate that one canproduce atomically smooth 1 nmthickCNxovercoatswith acceptable corrosionperformance. In addition, this paper shows that, with the proper choice of nanolayer thickness and process conditions, superhard coatings based on TiN/SiNx and TiB2/TiC multilayers with high thermal stability, low internal stress, and high wear resistance can be synthesized.
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References
M. Y. Chen et al., “Synthesis andTribological Properties of Carbon Nitride as a Novel Superhard Coating and Solid Lubricant,”Tribology Transactions, 36 (3) (1993), pp. 491–495.
E.C. Cutiongco et al., “Tribological Behavior of Amorphous Carbon Nitride Overcoats for Magnetic Thin-Film Rigid Disks,”Journal of Tribology—Transactions of the ASME, 118 (3) (1996), pp. 543–548.
T.W. Schar et al., “Structural and Tribological Characterization of Protective Amorphous Diamond-Like Carbon and Amorphous CNx Overcoats for Next Generation Hard Disks,”J. Applied Physics, 85 (6) (1999), pp. 3142–3154.
W.C. Chan et al., “Synthesis, Composition, Surface Roughness and Mechanical Properties of Thin Nitrogenated Carbon Films,”J. Vacuum Science & Technology A—Vacuum Surfaces and Films, 16 (3) (1998), pp. 1907–1911.
M.U. Guruzetal., “Corrosion Performance of Ultrathin Carbon Nitride Overcoats Synthesized by Magnetron Sputtering,”Thin Solid Films, 381 (1) (2001), pp. 6–9.
U. Helmersson et al., “Adhesion of Titanium Nitride Coatings on High-Speed Steels,”J. Vacuum Science & Technology A—Vacuum Surfaces and Films, 3 (2) (1985), pp. 308–315.
J.E. Sundgren, “Structure and Properties of TiN Coatings,”Thin Solid Films, 128(1-2) (1985), pp.21–44.
A. Karimi et al., “Characterisation of TiN Thin Films Using the Bulge Test and the Nanoindentation Technique,”Thin Solid Films, 308 (1997), pp. 334–339.
D. Li et al., “Synthesis of Superhard Carbon Nitride Composite Coatings,”Applied Physics Letters, 67 (2) (1995), pp. 203–205.
D. Li et al., “Structure and Hardness Studies of CNx/TiN Nanocomposite Coatings,”Applied Physics Letters, 68 (9) (1996), pp. 1211–1213.
A. Madan et al., “Stabilization of Cubic AIN in Epitaxial AIN/TiN Superlattices,” Physical Review Letters, 78 (9) (1997), pp. 1743–1746.
M. Ohring,The Materials Science of Thin Films(New York: Academic, 1992).
V. Novotny and N. Staud, “Correlation Between Environmental and Electrochemical Corrosion of Thin-Film Magnetic Recording Media,”J. Electrochemical Society, 135 (12) (1988), pp. 2931–2938.
J. F Ying, T. Anoikin, and C. Martner, “Evolution of the Corrosion Process on Thin-Film Media,”J. Vacuum Science & Technology A—Vacuum SurfacesandFilms, 18 (4) (2000), pp. 1804–1808.
S. Veprek, S. Reiprich, and S.H. Li, “Superhard Nanocrystalline Composite-Materials—The TiN/Si3N4 System,”Applied Physics Letters, 66 (20) (1995), pp. 2640–2642.
M.M. Lacerda et al., “Synthesis of Hard TiN Coatings with Suppressed Columnar Growth and Reduced Stress,”J. Vacuum Science & Technology A—Vacuum Surfaces and Films, 17 (5) (1999), pp. 2915–2919.
D. Li et al., “Structure and Hardness Studies of CNx/TiN Nanocomposite Coatings,”Applied Physics Letters, 68 (9) (1996), pp. 1211–1213.
I.A. Polonsky et al., “A Study of Rolling-Contact Fatigue of Bearing Steel Coated with Physical Vapor Deposition TiN Films: Coating Response to Cyclic Contact Stress and Physical Mechanisms Underlying Coating Effect on the Fatigue Life,”Wear, 215 (1-2) (1998), pp. 191–204.
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Lee, K.W., Li, DJ. & Chung, YW. Nanolayer coatings for hard disk and demanding tribological applications. JOM 54, 49–52 (2002). https://doi.org/10.1007/BF02709095
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DOI: https://doi.org/10.1007/BF02709095