Abstract
A series of interpenetrating polymer networks (IPNs) of castor oil based polyurethane/polyacrylonitrile (PU/PAN: 80/20, 60/40, 50/50, 40/60 and 20/80) were synthesized by condensation reaction of castor oil with methylene diisocyanate and acrylonitrile, employing benzoyl peroxide (BPO) and ethylene glycol dimethylacrylate (EGDM) as initiator and crosslinkers respectively. The physical, chemical, optical and some of the mechanical properties of PU/PAN were studied. Phase stabilization in IPNs was investigated by wide angle X-ray (WAXS) profile analysis. Variation of crystal size distribution was studied in these polymer networks.
Similar content being viewed by others
References
Balzer D and Ledbetter H J 1992J. Mater. Sci. Lett. 11 1419
Frisch H L, Klempher D and Frisch K C 1969J. Polym. Sci. Part B 7 775
Frisch H L, Frisch K C and Klempner D 1981Pure Appl. Chem. 53 1557
Hindeleh A M and Hosemann R 1991J. Mater. Sci. 26 5127
Hosemann R 1988Prog. Coll. Polym. Sci. 77 15
Hourston D J and Zia Y 1984J. Appl. Polym. Sci. 29 629
Naughton F C 1974J. Am. Oil Chem. Soc. 51 65
Patel M and Suthar B 1987J. Appl. Polym. Sci. 34 2037
Patel P, Patel M and Suthar B 1988Br. Polym. J. 20 525
Press W, Flannery B P, Teakolsley S and Veeterling W T 1986Numerical recipes (U.K.: CVP) p. 83
Siddaramaiah, Mallu P and Somashekar R 1998J. Appl. Polym. Sci. 68 1739
Somashekar R and Somashekarappa H 1997J. Appl. Crystal. 30 147
Sooryanarayana K, Somashekar R and Guru Row T N 1997Solid State Ionics 104 319
Sperling L H 1981Interpenetrating polymer networks and related materials (New York: Plenum Press)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mallu, P., Siddaramaiah & Somashekar, R. Synthesis and characterization of castor oil based polyurethane-polyacrylonitrile interpenetrating polymer networks. Bull Mater Sci 23, 413–418 (2000). https://doi.org/10.1007/BF02708392
Issue Date:
DOI: https://doi.org/10.1007/BF02708392