Abstract
We measured vapor-liquid equilibria (VLE) for the system of pentafluoroethane (HFC125)-difluoroethane (HFC152a) over the temperature range from 268.15 K to 373.15 K. Fitting VLE data obtained to an extended BWR equation of state, binary interaction parameters were correlated as a linear function of temperature. Applying the equation of state including the binary interaction parameters to refrigeration cycle, estimation of coefficient of performance (COP) revealed about 13.3 % energy-saving against chlorodifluoromethane (HCFC22), when the mole fraction of HFC125 is 0.44. As the condition of COP estimation, we assumed that temperature changes of out-side fluids were from 285.15 down to 280.15 K and 305.15 up to 310.15 K with 3 K in minimum temperature difference, respectively.
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References
Nishiumi, H., Komatsu, M., Yokoyama, T. and Kohmatsu, S., “Two-and Three-Phase Equilibria and Critical Locus For The System of HCFC22-HFC32”,Fluid Phase Equilibria,83, 109 (1993).
Nishiumi, H., “Vapor-Liquid Equilibrium Calculation of Systems Containing Hydrogen by Extended BWR Equation of State”,J. Chem. Eng. Japan,16, 449 (1984).
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Nishiumi, H., Akita, H. & Akiyama, S. High pressure vapor-liquid equilibria for the HFC125-HFC152a system. Korean J. Chem. Eng. 14, 359–364 (1997). https://doi.org/10.1007/BF02707052
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DOI: https://doi.org/10.1007/BF02707052