Skip to main content
Log in

Increasing the conversion fraction of sulfur to sodium thiosulfate with the ultrasound energy

  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

The usage of ultrasound has gained popularity in the recent years. Ultrasonic processing means blasting liquids, usually water, with very intense sound at high frequency, producing very well mixed powerful chemical and physical reactions. This paper deals with the investigation of the effect of ultrasonic energy on the conversion fraction of sulfur in the production reaction of sodium thiosulfate which was obtained from sulfur and Na2SO3 solution. Concentration of Na2SO3 solution parameter was chosen as the constant parameter. The experiments were performed with various amplitudes of ultrasound power and in the absence and presence of ultrasound energy in various temperatures with various particle sizes. The results indicate that the conversion fraction values increase in the presence of ultrasound energy and increase at high amplitude values.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Atchley, A. A. and Crum, L. A.,Acoustic cavitation and bubble dynamics, in ultrasound: its chemical physical and biological effects, ed K. S. Suslick, VCH, Weinheim (1988).

    Google Scholar 

  • Awate, S. V., Waghmode, S. B., Patil, K. R., Agashe, M. S. and Joshit, P. N., “Influence of preparation parameters on characteristics of zirconia-pillared clay using ultrasonic technique and its catalytic performance in phenol hydroxylation Reaction,”Korean J. Chem. Eng.,18, 257(2001).

    Article  CAS  Google Scholar 

  • Ceccio, S. L. and Brennen, C. E.,“Observations of the dynamics and acoustics of travelling bubble cavitation,”J. Fluid Mech.,233, 633 (1991).

    Article  CAS  Google Scholar 

  • Choi, J. H. and Kim, S. B.,“Effect of ultrasound on sulfuric acid-catalysed hydrolysis of starch,”KoreanJ. Chem. Eng.,11, 178 (1994).

    Article  CAS  Google Scholar 

  • Donatti, D. A., Ruiz, A. I. and Vollet, D. R.,“A dissolution and reaction modeling for hydrolysis of TEOS in heterogeneous TEOS-water-HCl mixtures under ultrasound stimulation,”Ultrasonics Sonochemistry,9(3), 133(2001).

    Article  Google Scholar 

  • Faid, F., Contamine, F., Wilhelm, A. M. and Delmas, H.,“Comparison of ultrasound effects in different reactors at 20 kHz,”Ultrasonics Sonochemistry,5(3), 119 (1998).

    Article  CAS  Google Scholar 

  • Hagenson, L. C. and Doraiswamy, L. K.,“Comparison of the effects of ultrasound and mechanical agitation on a reacting solid-liquid system,”Chemical Engineering Science,53(1), 131 (1998).

    Article  CAS  Google Scholar 

  • Iliev, V., Prahov, L., Bilyarska, L., Fischer, H., Schulz-Ekloff, G., Wöhrle, D. and Petrov, L., “Oxidation and photooxidation of sulfide and thiosulfate ions catalyzed by transition metal chalcogenides and phthalocyanine complexes,”Journal of Moleculer Catalysis A: Chemical,151(1–2), 161 (2000).

    Article  CAS  Google Scholar 

  • Inoue, T., Mori, K., Kageyama, Y. and Mori, H.,“Various growth shapes of Na2S2O3.5H2O crystals,”Crystal Research and Technology,35, 587(2000).

    Article  CAS  Google Scholar 

  • Kim, I. K., Yoa, S. J. and Lee, J. K., “Reaction pathways and kinetic modeling for sonochemical decomposition of benzothiophene,”Korean J. Chem. Eng.,20, 1045 (2003).

    Article  CAS  Google Scholar 

  • Lyczko, N., Espitalier, F., Louisnard, O. and Schwartzentruber, J.,“Effect of ultrasound on the induction time and the metastable zone widths of potassium sulfate,”Chemical Engineering Journal,86(3), 233 (2002).

    Article  CAS  Google Scholar 

  • Mason, T. J.,The uses of ultrasound in chemistry, Sonochemistry, Royal Society of Chemistry (1990).

  • Mason, T. J. and Lorimer, J. P.,Theory. Applications and uses of ultrasound in chemistry, Sonochemistry, Ellis Horwood (1989).

    Google Scholar 

  • Okur, H., Tekin, T., Ozer, A. and Bayramoglu, M.,“Effect of ultrasound on the dissolution of colemanite in H2SO4,”Hydrometallurgy,67, 79 (2002).

    Article  CAS  Google Scholar 

  • Qin, W., Yuan, Y. H. and Dai, Y. Y.,“Effect of ultrasound on desorption equilibrium,”Chinese Journal of Chemical Engineering,9(4), 427 (2001).

    CAS  Google Scholar 

  • Shah, Y. T., Pandit, A. B. and Moholkar, V. S.,Cavitation reaction engineering, The Plenum Chemical Engineering Series, Kluwer Academic/Plenum Publishers, LoC 99-37362, ISBN 0-306-46141-2 (2000).

  • Sivakumar, M., Tatake, P. A. and Pandit, A. B.,“Kinetics of p-nitrophenol degradation: effect of reaction conditions and cavitational parameters for a multiple frequency system,”Chemical Engineering Journal,85(2-3), 327 (2002).

    Article  CAS  Google Scholar 

  • Snell, F. D. and Biffen, F. M.,Commercial methods of analysis, Mc Graw-Hill, New York, 753 (1944).

    Google Scholar 

  • Suslick, K. S.,The chemistry of ultrasound, The Yearbook of Science & the Future (1994).

  • Tekin, T.,“Use of ultrasound in the dissolution kinetics of phosphate rock in HCl,”Hydrometallurgy,64, 187 (2002).

    Article  CAS  Google Scholar 

  • Woo, J., Lee, C., Hong, Y., Yoon, Y., Hahm, Y. and Chang, Y., “Effects of ultrasound on synthesis of mullite by sol-gel processes,”Journal of the Korean Institute of Chemical Engineers,34(2), 208 (1996).

    CAS  Google Scholar 

  • Yun, C. Y., Chah, S., Kang, S. K. and Yi, J.,“The effect of ultrasonic waves on the fabrication of TiO2 nanoparticles on a substrate using a self-assembly method,”Korean J. Chem. Eng,21, 1062 (2004).

    Article  CAS  Google Scholar 

  • Zhao, J. H.,“Effect of ultrasound on aluminium trihydroxide crystallization from sodium aluminate solution,”Acta Chimica Sinica,60(1), 81 (2002).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Tuba İngeç.

Rights and permissions

Reprints and permissions

About this article

Cite this article

İngeç, T., Tekin, T. Increasing the conversion fraction of sulfur to sodium thiosulfate with the ultrasound energy. Korean J. Chem. Eng. 23, 731–735 (2006). https://doi.org/10.1007/BF02705919

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02705919

Key words

Navigation