Abstract
An Extractant Impregnated Resin (EIR) was prepared by impregnation of Aliquat 336 into Amberlite XAD-4 for tentative separation of rhenium from rhodium in nitric acid solution. An optimum loading ratio of the XAD-4 resin for Aliquat 336 was found to be about 0.4 (g Aliquat 336/g resin). The prepared EIR showed high preference for rhenium over rhodium and adsorption isotherms for rhenium were described well by Langmuir equation in both the single and multi-component systems. Maximum adsorption capacities obtained by modeling the isotherms of rhenium were 2.01 and 1.97 meq/g for the single and the multi-component systems, respectively. On the other hand, only little adsorption of rhodium ions was observed. The homogeneous model fitted the kinetic data quite well and the obtained effective diffusivities of rhenium and rhodium ions were on the order of 10-7 and 10-6 cm2 min-1, respectively.
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Alonso, A. I. and Pantelides, C. C., “Modeling and simulation of impregnated membrane processes for recovery of Cr(VI) with Aliquat 336,”J. of Membrane Science,110, 151 (1996).
Asakura, T., Hotoku, S., Ban, Y., Kim, S. Y., Mineo, H. and Morita, Y.,Research on PARC for future reprocessing, ATLANTE 2004, Nimes, 012-04(2004).
Beauvais, R. B. and Alexandratos, S. P., “Polymer-supported reagents for the selective complexatio of metal ions: an overview,”Reactive & Polymers,36, 113 (1998).
Belyaev, A. V., Renard, E. V., Khraanenko, S. P., Emel’yanov, V. A. and Fedotov, M. A., “State of radiorhodium in high-level liquid waste from regeneration of spent nuclear fuel,”Radiochemistry,44(6), 546 (2002).
Cortina, J. L. and Warshawsky, A., “Developments in solid-liquid extraction by solvent-impregnated resins,”Ion Exchange and Solvent Extraction,13, 195 (1997).
Fontas, C., Salvado, V. and Hidalgo, M., “Solvent extraction of Pt(IV) by Aliquat 336 and its application to solid supported liquid membrane system,”Solvent Extraction and Ion Exchange,17(1), 149 (1999).
Jerabek, K., Hankova, L., Strikovsky, A. G. and Warshawsky, “Solvent impregnated resin: relation between impregnation process and polymer support morphology I. di-(2-ethylhexyl)dithiophosphoric acid,”Reactive & Functional Polymer,28, 201 (1996).
Kim, H. T., Lee, C. H., Shul, Y.G., Moon, J. K. and Lee, E. H., “Evaluation of PAN-TiO2 composite adsorbent for removal of Pb(II) ion in aqueous solution,”Separation Science and Technology,38(3), 695 (2003).
Moon, J.-K., Lee, E.-H., Han, Y.-J., Lee, B.-C. and Kim, H.-T., “Multi-component ion exchange kinetics with PAN-KCoFC ion exchanger,KoreanJ. Chem. Eng.,22, 127 (2005).
Panesko, J. V.,Recovery of rhodium, palladium and technetium on strongly basic anion exchange resin, ARH-1279 (1969).
Robinson, S. M., Arnold, W. D. and Byers, C. H., “Mass-transfer mechanisms for zeolite ion exchange in wastewater treatment,”AIChE J.,40(12), 2045 (1994).
Rovira, M., Cortina, J. L., Arnaldos and Sastre, A. M., “Recovery and separation of platinum group metals using impregnated resins containing Alamine 336,”Solvent Extraction and Ion Exchange,16(5), 1279 (1998).
Saha, B., Gill, R. J., Bailey, D. G., Kabay, N. and Arda, M., “Sorption of Cr(VI) from aqueous solution by amberlite XAD-7 resin impregnated with Aliquat 336,”Reactive & Functional Polymers,60, 223 (2004).
Taylor, R. J. and May, I., “Advances in actinide and technetium kinetics for applications in process flowsheet modeling,”Separation Science and Technology,36(5&6), 1225 (2001).
Uchida, S. and Tagami, K., “Separation and concentration of technetium using a Tc-selective extraction chromatographic resin,”J. of Radioanalytical and Nuclear Chemistry,221(1–2), 35 (1997).
Varentosov, V. K. and Varentosova, V. I., “Electrodeposition of rhodium on cathodes of carbon-fiber material from Rh(III) complexes in nitric acid solutions,”Russian J. of Electrochemistry,39(6), 703 (2003).
Villadsen, J. and Michelsen, M L.,Solution of differential equation models by polynomial approximation, Prentice-Hall, Englewood Cliff, NJ (1978).
Wei, Y., Arai, T., Kumagai, M. and Bruggeman, A.,Development of the ERIX process for reprocessing spent FBR-MOX fuel, Global 2003, New Orleans, LA,479 (2003).
Yang, W.W., Luo, G S. and Gong, X. C., “Extraction and separation of metal ions by a column packed with polystyrene microcapsules containing Aliquat 336,”Separation and Purification Technology,43, 175 (2005).
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Moon, JK., Han, YJ., Jung, CH. et al. Adsorption of rhenium and rhodium in nitric acid solution by Amberlite XAD-4 impregnated with Aliquat 336. Korean J. Chem. Eng. 23, 303–308 (2006). https://doi.org/10.1007/BF02705732
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DOI: https://doi.org/10.1007/BF02705732