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Chemistry of selected cyclic P(III) compounds possessing a P-Cl bond

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Abstract

The compounds [CH2(6-t-Bu-4-Me-C6H2O)2]PCl (1), (OCH2CMe2CH2O)-PCl (2), and [ClPN(t-Bu)]2 (3) have been utilized as precursors in the synthesis of (i) new pentacoordinate phosphorus compounds [e.g. CH2(6-t-Bu-4-Me-C6H2O)2 P(NRR′)(O2C6C14), CH2(6-t-Bu-4-Me-C6H2O)2PX[OC(O-i-Pr)N=N(C(O)O-i-Pr)],(ii) cyclic phosphates and their complexes [e.g. imidazolium+CH2(6-t-Bu-4-Me-C6H2O)2PO2 -.MeOH], (iii) new cycloaddition products [e.g. CH2(6-t-Bu-4-Me-C6H2O)2PC(CO2Me)C(CO2Me)C(O)N, (iv) macrocyclic compounds [e.g. [(t-BuN)P]2[-OCH2CMe2CH2O-]h2] and (v) phosphonates [e.g. (OCH2CMe2CH2O)P (O)CH2C(CN)=CHC5H4FeC5H5]. The synthetic and structural aspects of these new products are discussed.

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Authors and Affiliations

  1. School of Chemistry, University of Hyderabad, 500 046, Hyderabad, India

    K. C. Kumaraswamy, Sudha Kumaraswamy, Praveen Kommana, N. Satish Kumar & K. Senthil Kumar

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  1. K. C. Kumaraswamy
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  2. Sudha Kumaraswamy
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  3. Praveen Kommana
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  4. N. Satish Kumar
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Kumaraswamy, K.C., Kumaraswamy, S., Kommana, P. et al. Chemistry of selected cyclic P(III) compounds possessing a P-Cl bond. J Chem Sci 114, 367–377 (2002). https://doi.org/10.1007/BF02703827

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