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Intramolecular electron transfer in mixed-valence complexes [(NH3)5Ru-L-Ru(NH3)5]5+ (L = N2, pyz, pym, 4,4’-bipy, bpa)

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Foundations of Physics Letters

Abstract

The dynamics of the intramolecular electron transfer from Ru(II) to Ru(III) in binuclear mixed-valence complexes [NH3)5Ru -L-Ru(NH3)5]5+ (L = N2, pyz, bipy, pym, bpa) is analyzed by the semiempirical CINDO + CI method.

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Translated from ZhurnalStruktumoi Khimii, Vol. 39, No. 4, pp. 579–590, July–August, 1998.

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Sizova, O.V., Baranovskii, V.I., Panin, A.I. et al. Intramolecular electron transfer in mixed-valence complexes [(NH3)5Ru-L-Ru(NH3)5]5+ (L = N2, pyz, pym, 4,4’-bipy, bpa). Found Phys Lett 15, 471–479 (2002). https://doi.org/10.1007/BF02701374

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