Skip to main content
Log in

Anisotropy of lattice distortion of [Co(NH3)5NO2]C2O4 at hydrostatic pressures of up to 4.0 GPa

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Variation of the lattice parameters of [Co(NH3)5NO2]C2O4 as a function of hydrostatic pressure was studied by powder X-ray diffractom etry in diamond anvils. No phase transitions were observed at pressures below 4.0 GPa, but the structure was anisotropically distorted. The maximal compression was observed in the direction perpendicular to the planes of the oxalate ions and NO2 ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. V. Boldyreva, H. Ahsbahs, and H. Uchtmann,Ber. Bunseng. Phys. Chem.,98, No. 5, 738–745 (1994).

    CAS  Google Scholar 

  2. E. V. Boldyreva, D. Yu. Naumov. and H. Ahsbahs,Z. Krist., Suppl. Issue,B11, 76 (1996).

    Google Scholar 

  3. E. V. Boldyreva, S. L. Kuzmina, and H. Ahsbahs,Zh. Strukt. Khim.,39, No. 3, 424–432 (1998).

    Google Scholar 

  4. E. V. Boldyreva, D. Yu. Naumov, and H. Ahsbahs,ibid., 433–447.

  5. E. V. Boldyreva, H. Ahsbahs. D. Yu. Naumov, and A. Kutoglu.Acta Crystallogr.,C54, 1378–1383 (1998).

    CAS  Google Scholar 

  6. E. V. Boldyreva, D. Yu. Naumov. and H. Ahsbahs,ibid.,B54, 798–808 (1998).

    CAS  Google Scholar 

  7. E. V. Boldyreva, J. Kivikoski. and J. A. K. Howard,ibid.,B53, 394–404 (1997).

    CAS  Google Scholar 

  8. E. V. Boldyreva, J. Kivikoski, and J. A. K. Howard,ibid., 405–414.

  9. P. B. Novikov, D. Yu. Naumov. E. V. Boldyreva, and N. V. Podberezskaya,Zh. Strukt. Khim.,39, No. 3, 412–423 (1998).

    Google Scholar 

  10. G. MÄueler,Prax. Naturwiss. Chem. Köln,3, 81–86 (1981).

    Google Scholar 

  11. C. E. Weir, S. Block, and G. J. Piermarini,J. Res. Natl. Bur. Stand.,69C, 275–281 (1965).

    Google Scholar 

  12. G. J. Piermarini, S. Block, and J. D. Barnett,J. Appl. Phys.,44, 5377–5382 (1973).

    Article  CAS  Google Scholar 

  13. H. K. Mao, J. Xu, and P. M. Bell,J. Geophys. Res.,91, 4673–4676 (1986).

    Article  CAS  Google Scholar 

  14. R. Brüggemann, B. Müller, T. Debaerdemaeker, et al.,Program Complex for X-Ray Crystallography ULM, Ulm University, Germany (1992).

    Google Scholar 

  15. R. Hazen and L. Finger,Comparative Crystal Chemistry. Temperature, Pressure, Composition, and the Variation of Crystal Structure, Wiley (1982).

  16. A. V. Virovets and N. V. Podberezskaya,Kristallografiya,37, No. 4, 1017–1019 (1992).

    CAS  Google Scholar 

  17. E. V. Boldyreva, in:Reactivity of Solids. Past, Present, Future, V. V. Boldyrev (ed.), Blackwells, (1996), pp. 141–184.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Boldyreva, E.V., Kuzmina, S.L., Novikov, P.B. et al. Anisotropy of lattice distortion of [Co(NH3)5NO2]C2O4 at hydrostatic pressures of up to 4.0 GPa. J Struct Chem 40, 899–904 (1999). https://doi.org/10.1007/BF02700698

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02700698

Keywords

Navigation