Abstract
Variation of the lattice parameters of [Co(NH3)5NO2]C2O4 as a function of hydrostatic pressure was studied by powder X-ray diffractom etry in diamond anvils. No phase transitions were observed at pressures below 4.0 GPa, but the structure was anisotropically distorted. The maximal compression was observed in the direction perpendicular to the planes of the oxalate ions and NO2 ligands.
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E. V. Boldyreva, H. Ahsbahs, and H. Uchtmann,Ber. Bunseng. Phys. Chem.,98, No. 5, 738–745 (1994).
E. V. Boldyreva, D. Yu. Naumov. and H. Ahsbahs,Z. Krist., Suppl. Issue,B11, 76 (1996).
E. V. Boldyreva, S. L. Kuzmina, and H. Ahsbahs,Zh. Strukt. Khim.,39, No. 3, 424–432 (1998).
E. V. Boldyreva, D. Yu. Naumov, and H. Ahsbahs,ibid., 433–447.
E. V. Boldyreva, H. Ahsbahs. D. Yu. Naumov, and A. Kutoglu.Acta Crystallogr.,C54, 1378–1383 (1998).
E. V. Boldyreva, D. Yu. Naumov. and H. Ahsbahs,ibid.,B54, 798–808 (1998).
E. V. Boldyreva, J. Kivikoski. and J. A. K. Howard,ibid.,B53, 394–404 (1997).
E. V. Boldyreva, J. Kivikoski, and J. A. K. Howard,ibid., 405–414.
P. B. Novikov, D. Yu. Naumov. E. V. Boldyreva, and N. V. Podberezskaya,Zh. Strukt. Khim.,39, No. 3, 412–423 (1998).
G. MÄueler,Prax. Naturwiss. Chem. Köln,3, 81–86 (1981).
C. E. Weir, S. Block, and G. J. Piermarini,J. Res. Natl. Bur. Stand.,69C, 275–281 (1965).
G. J. Piermarini, S. Block, and J. D. Barnett,J. Appl. Phys.,44, 5377–5382 (1973).
H. K. Mao, J. Xu, and P. M. Bell,J. Geophys. Res.,91, 4673–4676 (1986).
R. Brüggemann, B. Müller, T. Debaerdemaeker, et al.,Program Complex for X-Ray Crystallography ULM, Ulm University, Germany (1992).
R. Hazen and L. Finger,Comparative Crystal Chemistry. Temperature, Pressure, Composition, and the Variation of Crystal Structure, Wiley (1982).
A. V. Virovets and N. V. Podberezskaya,Kristallografiya,37, No. 4, 1017–1019 (1992).
E. V. Boldyreva, in:Reactivity of Solids. Past, Present, Future, V. V. Boldyrev (ed.), Blackwells, (1996), pp. 141–184.
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Boldyreva, E.V., Kuzmina, S.L., Novikov, P.B. et al. Anisotropy of lattice distortion of [Co(NH3)5NO2]C2O4 at hydrostatic pressures of up to 4.0 GPa. J Struct Chem 40, 899–904 (1999). https://doi.org/10.1007/BF02700698
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DOI: https://doi.org/10.1007/BF02700698