Abstract
This study is related to the investigation of the chemical fixation of carbon dioxide to copolymers bearing a cyclic carbonate group and their application to polymer blends. In the synthesis of (2-oxo-l,3-dioxolan4-yl) methyl vinyl ether (OVE) from glycidyl vinyl ether (GVE) and CO2, quaternary ammonium salt catalysts showed good yield of OVE. The results with long alkyl chain and with lower accessibility showed a higher catalytic activity. Mixed catalyst of PEG-4000 and Nal showed higher catalytic activity than Nal alone. The copolymer of OVE and acrylonitrile (AN) was prepared by radical copolymerization in acetonitrile at 60 °C. The monomer reactivity ratios were given as r1(OVE)=0.36 and r2(AN)=1.21 in the copolymerization of OVE and AN. The films of poly(OVE-co-AN)/PVC blends were cast from DMF. The poly(OVE-co-AN)/PVC blends showed good miscibility over whole composition ranges.
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References
Brandrup, J. and Immergut, E. H., “Polymer Handbook,” John Wiley & Sons, New York (1989).
Inoue, S., Yamazaki, N. and Higashi, F., “Organic and Bioorganic Chemistry of Carbon Dioxide,” Kodansha Ltd., Tokyo (1982).
Kihara, N., Hara, N. and Endo, T., “Catalytic Activity of Various Salts in the Reaction of 2,3-Epoxypropyl Phenyl Ether and Carbon Dioxide under Atmospheric Pressure,”J. Org. Chem.,58, 6198(1993).
Moon, J. Y, Yang, J. G., Jung, S. M., Park, D. W. and Lee, J. K., “A Kinetic Study on the Reaction between Glycidyl Vinyl Ether and Carbon Dioxide with Quaternary Ammonium Salts as Catalyst,”React. Kinet. & Cat. Lett.,61(2), 315 (1997).
Nishikubo, T., Kameyama, A. and Sasano, M., “Synthesis of Functional Polymers Bearing Cyclic Carbonate Groups from (2-Oxo-l,3-dioxolan-4-yl)methyl Vinyl Ether,”J. Polym. Sci., A: Polym. Chem.,32, 301(994).
Nomura, R., Ninagawa, A. and Matsuda. H., “Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides in the presence of Organoantimony Compounds as Novel Catalysts,”J. Org. Chem.,45, 3735 (1980).
Odian, G., “Principles of Polymerization,” John Wiley & Sons, New York (1991).
Park, D. W., Moon, J. Y, Yang, J. G., Jung, S. M. and Lee J. K., “Catalytic Conversion of Carbon Dioxide to Polymer Blends via Cyclic Carbonate,”Studies in Surface Science and Catalysis,114, 403(1998).
Park, D. W, Park, S. W, Kaseger, C. E, Moon, J. Y. and Lee, J. B., “Absorption and Reaction of CO2 with 2,3-Epoxypropyl Phenyl Ether Using Aliquat 336 as Catalyst,”React. Kinet. & Cat. Lett.,62(2),243(1997).
Randall, J. C, “Polymer Sequence Determination-Carbon 13 NMR Method,” Academic Press, New York (1977).
Rokicki, G., Kuran, W. and Marciniak, B. P., “Cyclic Carbonates from Carbon Dioxide and Oxiranes,”Monat. Chem.,115, 205 (1984).
Starks, C. M., Liotta, C. L. and Halpem, M., “Phase Transfer Catalysis,” Chapman & Hall, New York(1994).
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Moon, JY., Jang, HJ., Kim, KH. et al. Chemical fixation of carbon dioxide to copolymers bearing cyclic carbonate group. Korean J. Chem. Eng. 16, 721–724 (1999). https://doi.org/10.1007/BF02698342
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DOI: https://doi.org/10.1007/BF02698342