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Preparation of NiO-ZrO2/SO -24 catalyst and its catalytic activity for ethylene dimerization

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Abstract

NiO-ZrO2/SO -24 catalysts were prepared by coprecipitation from the solution of nickel chloride -zirconium oxychloride mixture followed by treating with H2SO4 NiO-ZrO2 alone without SO -24 was inactive as a catalyst for ethylene dimerization, but NiO-ZrO2/SO -24 was found to be very active even at room temperature. The high catalytic activity of NiO-ZrO2/SO -24 was closely correlated with the increase of acid strength by the inductive effect of sulfate ion adsorbed on NiO-ZrO2. The decrease of catalytic activity above 150‡C of evacuation temperature was explained in terms of the structural change of catalyst from amorphous phase to crystalline, and the sintering.

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References

  1. Hogan, J. P., Banks, R. L., Lanning, W. C. and Clark, A.:Ind. Eng. Chem.,47, 752 (1955).

    Article  CAS  Google Scholar 

  2. Uchida, H. and Imai, H.:Bull. Chem. Soc. Jap.,35, 989, 995 (1962), 38, 925 (1965).

    Article  CAS  Google Scholar 

  3. Sohn, J. R. and Ozaki, A.:J. Catal.,59, 303 (1979).

    Article  CAS  Google Scholar 

  4. Sohn, J. R. and Ozaki, A.:J. Catal.,61, 29 (1980).

    Article  CAS  Google Scholar 

  5. Wendt, G., Fritsch, E., Schöllner, R. and Siegel, H.:Z. Anorg. Allg. Chem.,467, 51 (1980).

    Article  CAS  Google Scholar 

  6. Flinv, R. A., Larson, O. A. and Beuther, H.:Ind. Eng. Chem.,52, 153 (1960).

    Article  Google Scholar 

  7. Berndt, G. F., Thomson, S. J. and Webb, G.:J. Chem. Soc. Faraday Trans. I,79, 195 (1983).

    Article  CAS  Google Scholar 

  8. Herwijnen, T. V., Doesburg, H. V. and Jong, D. V.:J. Catal.,28, 391 (1973).

    Article  Google Scholar 

  9. Wendt, G., Hentschel, D., Finster, J. and Schöllner, R.:J. Chem. Soc. Faraday Trans. I.79, 2013 (1983).

    Article  CAS  Google Scholar 

  10. Ozaki, A. and Kimura, K.:J. Catal.,3, 395 (1964).

    Article  CAS  Google Scholar 

  11. Maruya, K. and Ozaki, A.:Bull. Chem. Soc. Japan,46, 351 (1973).

    Article  CAS  Google Scholar 

  12. Sohn, J. R. and Park, H. B.:J. Korean Chem. Soc.,26, 282 (1982).

    CAS  Google Scholar 

  13. Sohn. J. R. and Kim, H. J.:Bull. Korean Chem. Soc. 6, 248 (1985).

    CAS  Google Scholar 

  14. Sohn, J. R. and Kim. H. J.:J. Catal.,101, 428 (1986).

    Article  CAS  Google Scholar 

  15. Hino, M. and Arata, K.:J. C. S. Chem. Comm., 851 (1980).

  16. Torralvo, M. J., Alario, M. A. and Soria, J.:J. Catal.,86, 473 (1984).

    Article  CAS  Google Scholar 

  17. Clearfield, A.:Inorg. Chem,3, 146 (1964).

    Article  CAS  Google Scholar 

  18. Hüttig, G. F. and Pater, A.:Z. Anorg. Chem.,189, 183 (1930).

    Article  Google Scholar 

  19. Nakamoto, K.: “Infrared and Ramam Spectra of Inorganic and Coordination Compounds” 3rd Ed., P. 241, John Wiley & Sons, New York, (1978).

    Google Scholar 

  20. Parfitt, R. L. and Smart, R. St. C.:J. C. S Faraday I,73, 796 (1977).

    Article  CAS  Google Scholar 

  21. Tanabe, K.: “Solid Acids and Bases”, P. 55–106, Kodansa, Tokyo, (1970).

    Google Scholar 

  22. Kimura, K., A-l, H. and Ozaki, A.:J. Catal.,18, 271 (1970).

    Article  CAS  Google Scholar 

  23. Rabo, J. A., Angel, C. L., Kasai, P. H. and Schomaker, V.: Discuss. Faraday Soc.,41, 328 (1966).

    Article  Google Scholar 

  24. Parry, E. P.:J. Catal.,2, 371 (1963).

    Article  CAS  Google Scholar 

  25. Okazaki, S.: Senzo Sekkei (Japan), 94 (1982).

  26. Gillespie, R. J.: Accounts Chem. Res.,1, 202 (1968).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Industrial Chemistry, Engineering College, Kyungpook National University, 635, Taegu, Korea

    Jong Rack Sohn, Hae Won Kim & Jong Taik Kim

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  1. Jong Rack Sohn
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  2. Hae Won Kim
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  3. Jong Taik Kim
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Sohn, J.R., Kim, H.W. & Kim, J.T. Preparation of NiO-ZrO2/SO -24 catalyst and its catalytic activity for ethylene dimerization. Korean J. Chem. Eng. 4, 1–7 (1987). https://doi.org/10.1007/BF02698092

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  • DOI: https://doi.org/10.1007/BF02698092

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