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Characterization of 2:1 type layered aluminosilicate via intercalation reaction

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Abstract

The stable intercalation compounds were synthesized by ion exchange reaction of the cations (Ca2+, Mg2+, etc.) existing in the interlayer of the 2:1 type layered natural aluminosilicate with n-decylammonium ion and by successive molecular intercalation reaction of the primary n-alcanol (ROH, R = C10H21, C12 H25, C14H29).

The charge densities were calculated from the basal spacings of n-decylammonium derivatives under primary n-alcanol.

As the result, the aluminosilicates used in this study have the charge density of 0.25, 0.34 per formula unit and interlayer cation exchange capacity of 69.3, 92.4 meg./l00g, respectively.

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Authors and Affiliations

  1. Department of Ceramic Engineering, Yonsei University, 120, Seoul, Korea

    K. W. Hyung, J. H. Choy, C. E. Kim, Y. S. Park & J. W. Noh

  2. Department of Chemistry, College of Natural Science, Seoul National University, 120, Seoul, Korea

    J. H. Choy

  3. Devision of Chemistry, Korea Ginseng & Tobacco Research Institute, 120, Seoul, Korea

    Y. S. Park & J. W. Noh

Authors
  1. K. W. Hyung
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  2. J. H. Choy
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  3. C. E. Kim
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  4. Y. S. Park
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  5. J. W. Noh
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Hyung, K.W., Choy, J.H., Kim, C.E. et al. Characterization of 2:1 type layered aluminosilicate via intercalation reaction. Korean J. Chem. Eng. 1, 99–104 (1984). https://doi.org/10.1007/BF02697439

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  • DOI: https://doi.org/10.1007/BF02697439

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