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A new nanostructured material based on fluorophosphate incorporated into a zinc–aluminium layered double hydroxide by ion exchange

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Abstract

Layered double hydroxides (LDHs), also called anionic clays, consist of cationic brucite-like layers and exchangeable interlayer anions. These hydrotalcite-like compounds, with Zn and Al in the layers and chloride in the interlayer space, were prepared following the coprecipitation method at constant pH. The effect of pH, aging time and anion concentration on the intercalation of fluorophosphate \((\hbox {PO}_{3}\hbox {F}^{2-}\), FP) in the [Zn–Al] LDH was investigated. The best crystalline material, with high exchange extent, was obtained by carrying out the exchange at 25\({^{\circ }}\hbox {C}\) in a 0.03 M FP solution at pH 7 with at least 42 h of aging time. A mechanism for the FP intercalation was confirmed by X-ray diffraction, infrared spectroscopy and thermogravimetry (TG) analyses (TG and DTG curves).

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Authors and Affiliations

  1. Faculté des Sciences Semlalia, Cadi Ayyad University, BP 2390, 40000, Marrakech, Morocco

    El Hassan Elkhattabi, Moha Berraho & Layla El Gaini

  2. Ecole Normale Supérieure, Cadi Ayyad University, BP 2400, 40000, Marrakech, Morocco

    Mohamed Lakraimi

  3. International University of Grand-Bassam, BP 564, Grand Bassam, Côte d’Ivoire

    Ahmed Legrouri

  4. Al Akhawayn University, BP 104, 53000, Ifrane, Morocco

    Ahmed Legrouri

  5. Faculté des Sciences, Chouaib Doukkali University, BP 20, 24000, El Jadida, Morocco

    Radouan Hammal

Authors
  1. El Hassan Elkhattabi
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  2. Mohamed Lakraimi
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  3. Moha Berraho
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  4. Ahmed Legrouri
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  5. Radouan Hammal
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  6. Layla El Gaini
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Correspondence to Ahmed Legrouri.

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Elkhattabi, E.H., Lakraimi, M., Berraho, M. et al. A new nanostructured material based on fluorophosphate incorporated into a zinc–aluminium layered double hydroxide by ion exchange. Bull Mater Sci 40, 745–751 (2017). https://doi.org/10.1007/s12034-017-1414-0

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  • DOI: https://doi.org/10.1007/s12034-017-1414-0

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