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Fullerene compounds with transition metals MnC60: Preparation, structure, and properties

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Abstract

This review summarizes the results of studies on complexation of fullerene C60 with transition metals. The structural background for metal-fullerene interaction is discussed. Much attention is focused on the compounds MnC60. Methods of their preparation, structure, and properties are considered in detail. The nature of their catalytic activity is discussed.

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References

  1. R. Taylor, J. P. Hare, H. W. Kroto, et al., J. Chem. Soc, Chem. Commun., 1423-1425 (1990).

  2. H. Kroto, Nanotechnology, 3, 111–112 (1992).

    Article  Google Scholar 

  3. H. W. Kroto, J. R. Heath, S. C. O'Brien, et al., Nature, 318, 162–163 (1985).

    Article  CAS  Google Scholar 

  4. R. Baum, Chem. Eng. News, 72, No. 19, 5 (1994).

    Google Scholar 

  5. R. Dagani, ibid. 721994, No. 31, 4–5.

    Google Scholar 

  6. J. Theobald, M. Perrut, J.-V. Weber, et al., Supercond. Sci. Technol, 30, No. 14, 2783–2819 (1995).

    CAS  Google Scholar 

  7. A. W. Jensen, S. R. Wilson, and D. I. Schuster, Bioorg. Med. Chem., 4, 767 (1996).

    Article  Google Scholar 

  8. H. Nagashima, A. Nakaoka, S. Tajima, et al., Chem. Lett., 1361-1364 (1992).

  9. S. Serizawa, I. Gabrielova, Fujimoto, et al., J. Chem. Soc, Chem. Commun., 799-800 (1994).

  10. M. Wohlers, B. Herzog, A. Bauer, et al., 2nd International Workshop “Fullerenes and Atomic Clusters,” IWFAC-95, St. Petersburg (1995), p. 34.

  11. Y. Izumi, S. Hikazudani, and K.-I. Aika, Shokubai, 37, No. 6, 466–469 (1995) [Plat. Met. Rev., 40, No. 1, 43 (dy1996)].

    Google Scholar 

  12. J. B. Claridge, R. E. Douthwaite, M. L. H. Green, et al., J. Mol. CataL, 89, Nos. 1/2, 113–120 (1994).

    CAS  Google Scholar 

  13. A. S. Gurav, Z. Duan, L. Wang, et al., Chem. Mater, 5, 214–216 (1993).

    Article  CAS  Google Scholar 

  14. C. Dianbao, Z. Chuying, P. Guangzhe, et al., China Synth. Rubber Ind., 18, No. 4, 244 (1995).

    Google Scholar 

  15. P. N. D'yachkov, N. N. Breslavskaya, and E. G. Ippolitov, Dokl. Ross. Akad. Nauk, 334, No. 4, 455–457 (1994).

    Google Scholar 

  16. W. I. F. Davidet al.. Nature Land., 353, 156–158 (1991).

    Article  Google Scholar 

  17. J. W. Bausch, G. K. S. Prakash, G. A. Olah, et al., J. Am. Chem. Soc, 113, 3205–3206 (1991).

    Article  CAS  Google Scholar 

  18. P. W. Fowler and A. Ceulemans, J. Phys. Chem., 99, 508–510 (1995).

    Article  CAS  Google Scholar 

  19. R. C. Haddon, Phil. Trans. R. Soc. Lond. A, 343, 53–62 (1993).

    Article  CAS  Google Scholar 

  20. R. Taylor, ibid. 3431993, 87–101.

    Article  CAS  Google Scholar 

  21. F. Chen, D. Singh, and S. A. Jansen, J. Phys. Chem., 97, 10958 (1993).

    Article  CAS  Google Scholar 

  22. F. R. Hartley, Chem. Rev., 69, 799–844 (1969).

    Article  CAS  Google Scholar 

  23. P. M. Maitlis, The Organic Chemistry of Palladium, Vol. 1, Metal Complexes, Academic Press, New York (1971), pp. 106–174.

    Google Scholar 

  24. M. J. S. Dewar, Bull. Soc. Chim. France, 18, C79 (1954).

    Google Scholar 

  25. J. Chatt and L. A. Duncanson, J. Chem. Soc, Nos. 10/11, 2939-2947 (1953).

  26. M. J. S. Dewar and G. P. Ford, J. Am. Chem. Soc, 101, 783–791 (1979).

    Article  CAS  Google Scholar 

  27. L. S. Wang, J. Conceicao, C. Jin, et al., Chem. Phys. Lett., 182, 5–11 (1991).

    Article  CAS  Google Scholar 

  28. N. Koga and K. Morokuma, ibid., 202, 330–334 (1993).

    Article  CAS  Google Scholar 

  29. K. H. Lee, H. M. Lee, and W. R. Lee, Synth. Metals, 70, 1501–1502 (1995).

    Article  CAS  Google Scholar 

  30. C. Bo, M. Costas, and J. M. Poblet, J. Phys. Chem., 99, No. 16, 5914–5921 (1995).

    Article  CAS  Google Scholar 

  31. R. S. Ruoff, K. M. Kadish, P. Boulas, et al., ibid., 16, 8843–8850 (1995).

    Article  Google Scholar 

  32. P. J. Fagan, J. C. Calabrese, and B. Malone, Science, 252, 1160–1161 (1991).

    CAS  Google Scholar 

  33. Ref. 15 in [44].

  34. P. J. Fagan, J. C. Calabrese, and B. Malone, J. Am. Chem. Soc, 113, 9408–9409 (1991).

    Article  CAS  Google Scholar 

  35. V. V. Bashilov, B. L. Tumanskii, N. V. Petrovskii, et al., Izv. Ross. Akad. Nauk, Ser. Khim., 6, 1131–1134 (1994).

    Google Scholar 

  36. L. Pandolfo and M. Maggini, Abstracts of Papers from the 11th FECHEM Conference on Organometal Chemistry, Parma (1995), p. C223.

  37. P. J. Fagan, J. C. Calabrese, and B. Malone, Acc. Chem. Res., 25, 134–142 (1992).

    Article  CAS  Google Scholar 

  38. S. A. Lerke, B. A. Parkinson, D. H. Evans, et al., J. Am. Chem. Soc, 114, 7807–7813 (1992).

    Article  CAS  Google Scholar 

  39. B. Chase and P. J. Fagan, ibid. 1141992, 2252–2256.

    Article  CAS  Google Scholar 

  40. V. V. Bashilov, P. V. Petrovskii, V. I. Sokolov, et al., Organometallics, 12, 991–992 (1993).

    Article  CAS  Google Scholar 

  41. V. V. Bashilov, P. V. Petrovskii, V. I. Sokolov, et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2, 428–429 (1993).

    Google Scholar 

  42. T. V. Magdesieva, V. V. Bashilov, S. I. Gorelskii, et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2153-2158 (1994).

  43. A. L. Balch, V. J. Catalano, and J. W. Lee, Inorg. Chem., 30, 3980–3981 (1991).

    Article  CAS  Google Scholar 

  44. R. S. Koefod, M. F. Hudgens, and J. R. Shapley, J Am. Chem. Soc, 113, 8957–8958 (1991).

    Article  CAS  Google Scholar 

  45. Y. Zhu, R. S. Koefod, C. Devadoss, et al., Inorg. Chem., 31, 3505–3506 (1992).

    Article  CAS  Google Scholar 

  46. R. S. Koefod, C. Xu, W. Lu, et al., J. Phys. Chem., 96, 2928–2930 (1992).

    Article  CAS  Google Scholar 

  47. A. L. Balch, V. J. Catalano, J. W. Lee, et al., J. Am. Chem. Soc, 114, 5455–5457 (1992).

    Article  CAS  Google Scholar 

  48. A. L. Balch, J. W. Lee, B. C. Noll, et al., ibid. 1141992, 10984.

    Article  CAS  Google Scholar 

  49. A. L. Balch, J. W. Lee, and M. M. Olmsted, Angew. Chem. Int. Ed., 31, 1356 (1992).

    Article  Google Scholar 

  50. A. Vertes, M. Gal, F. E. Wagner, et al., Inorg. Chem., 32, 4478–4479 (1993).

    Article  CAS  Google Scholar 

  51. A. V. Usatov, E. V. Vorontsov, L. E. Vinogradova, et al., Izv. Ross. Akad. Nauk, Ser. Khim., 9, 1661–1665 (1994).

    Google Scholar 

  52. S. Schreiner, T. N. Gallaher, and H. K. Parsons, Inorg. Chem., 33, 3021–3022 (1994).

    Article  CAS  Google Scholar 

  53. A. L. Balch, J. W. Lee, B. C. Noll, et al., ibid. 331994, 5238–5243.

    Article  CAS  Google Scholar 

  54. A. V. Usatov, K. N. Kudin, E. V. Vorontsovz, et al., J. Organomet. Chem., 522, 147–153 (1996).

    Article  Google Scholar 

  55. A. L. Balch, J. W. Lee, B. C. Noll, et al., Inorg. Chem., 32, No. 17, 3577–3578 (1993).

    Article  CAS  Google Scholar 

  56. A. V. Usatov, A. L. Blumenfeld, E. V. Vorontsov, et al., Mendeleev Commun., 229-230 (1993).

  57. Y. Ishii, H. Hoshi, Y. Hamada, et al., Chem. Lett., 4, 801–804 (1994).

    Article  Google Scholar 

  58. R. E. Douthwaite, M. L. H. Green, A. H. H. Stephens, et al., J. Chem. Soc, Chem. Commun., 1522-1523 (1993).

  59. C. Christides, E. Devlin, A. Simopoulos, et al., J. Phys. Chem., 98, 11666–11668 (1994).

    Article  CAS  Google Scholar 

  60. S. I. Gorelskii, T. E. Magdesieva, and K. N. Butin, Izv. Ross. Akad. Nauk, Ser. Khim., 6, 1453–1457 (1996).

    Google Scholar 

  61. S. Ballenweg, R. Gleiter, and W. Kratschmer, Tetrahedron Lett., 34, 3737 (1993).

    Article  CAS  Google Scholar 

  62. A. P. Borisov, V. D. Makhaev, Yu. M. Shul'ga, et al., Synth. Metals, 70, Nos. 1-3, 1461–1462 (1995).

    Article  CAS  Google Scholar 

  63. V. K. Cherkasov, Yu. F. Radkov, M. A. Lopatin, et al., Izv. Ross. Akad. Nauk, Ser. Khim., 11, 1945–1947 (1994).

    Google Scholar 

  64. S. Zhang, T. L. Brown, Y. Du, et al., J. Am. Chem. Soc, 115, 6705–6709 (1993).

    Article  CAS  Google Scholar 

  65. M. Rasinkangas, T. T. Pakkanen, T. A. Pakkanen, et al., ibid. 1151994, 4901.

    Article  Google Scholar 

  66. A. L. Balch, V. J. Catalano, D. A. Costa, et al., J. Phys. Chem. Solids, 58, No. 11, 1633–1643 (1997).

    Article  CAS  Google Scholar 

  67. J. M. Hawkins, Acc Chem. Res., 25, 150–156 (1992).

    Article  CAS  Google Scholar 

  68. J. M. Hawkins, A. M. Meyer, T. A. Lewis, et al., J. Am. Chem. Soc, 114, 7954–7955 (1992).

    Article  CAS  Google Scholar 

  69. Y. C. Fann, D. Singh, and S. A. Jansen, J. Phys. Chem., 96, 5817–5818 (1992).

    Article  CAS  Google Scholar 

  70. W. Beck, H.-J. Bentele, and S. Huffer, Chem. Ber, 128, 1059–1060 (1995).

    Article  CAS  Google Scholar 

  71. M. D. Westmeyer, C. P. Galloway, and T. B. Rauchfuss, Inorg. Chem., 33, No. 6, 4615–4616 (1994).

    Article  CAS  Google Scholar 

  72. B. N. Tarasov, V. N. Fokin, A. P. Moravskii, et al., Izv. Ross. Akad. Nauk, Ser. Khim., 4, 679–682 (1997).

    Google Scholar 

  73. B. P. Tarasov, V. N. Fokin, A. P. Moravskii, et al., Zh. Neorg. Khim., 42, No. 6, 920–922 (1997).

    CAS  Google Scholar 

  74. H. Nagashima, A. Nakaoka, Y. Saito, et al., J. Chem. Soc, Chem. Commun., 377-379 (1992).

  75. V. B. Durasov, V. N. Ivanova, and A. A. Nikiforov, Abstracts of Papers from the 2nd Workshop “Fullerenes and Atomic Clusters” IWFAC-95, St. Petersburg (1995), p. 111.

  76. J. M. Cowley, M.-Q. Liu, B. L. Ramakrishna, et al.. Carbon, 32, No. 4, 746–748 (1994).

    Article  CAS  Google Scholar 

  77. V. A. Chernov, V. N. Ivanova, A. N. Kozhevnikova, et al., Nucl. Instr. Meth. Phys. Res., A359, 250–253 (1995).

    Google Scholar 

  78. V. N. Ivanova and L. A. Sheludyakova, Abstracts of Papers from the 2nd Workshop “Fullerenes and Atomic Clusters” IWFAC-95, St. Petersburg (1995), p. 161.

  79. V. B. Durasov, V. N. Ivanova, A. A. Nikiforov, et al., Abstracts of Papers from the 6th All-Russian Conference on Organometal Chemistry Devoted to the 100th Anniversary of Academician G. A. Razuvaev, Vol. 2, Nizhnii Novgorod (1995), p. 323.

  80. A. V. Okotrub, E. S. Fomin, V. N. Ivanova, et al., “Application of synchrotron radiation to materials science, III,” Mat. Res. Soc. Symp. Proc, 437, 155–159 (1996).

    Google Scholar 

  81. A. S. Lobach, B. N. Tarasov, Yu. M. Shulga, et al., Izv. Ross. Akad. Nauk, Sen Khim., 2, 483–484 (1996).

    Google Scholar 

  82. Yu. M. Shulga, A. S. Lobach, I. N. Ivleva, et al., Dokl. Ross. Akad. Nauk, 348, No. 6, 783–785 (1996).

    Google Scholar 

  83. H. Nagashima, Y. Kato, H. Yamaguchi, et al., Chem. Lett., 7, 1207–1210 (1994).

    Article  Google Scholar 

  84. T. Ukai, H. Kawazura, Y. Ishii, et al., J. Organomet. Chem., 65, 253–266 (1974).

    Article  CAS  Google Scholar 

  85. K. Moseley and P. M. Maitlis, J. Chem. Soc, D. Chem. Commun., 982-983 (1971).

  86. A. W. Ehlers and G. Frenking, Organometallics, 14, 423–426 (1995).

    Article  CAS  Google Scholar 

  87. J. Li, G. Schreckenbach, and T. Ziegler, J. Am. Chem. Soc, 117, 486–494 (1995).

    Article  CAS  Google Scholar 

  88. M. Poliakoff and J. J. Turner, J. Chem. Soc, Faraday Tmns. II, 70, 93–99 (1974).

    Article  CAS  Google Scholar 

  89. M. Rasinkangas, T. T. Pakkanen, and T. A. Pakkanen, J. Organomet. Chem., 476, C6-C8 (1994).

    Article  CAS  Google Scholar 

  90. T. Kodas and M. Hampden-Smith, The Chemistry of Metal CVD, VCH, Weinheim (1994).

  91. K. J. Klabunde, Acc. Chem. Res., 8, 393–399 (1975).

    Article  CAS  Google Scholar 

  92. A. D. Garnovskii, B. I. Harisov, G. Gohon-Zorrilla, et al., Usp. Khim., 64, No. 3, 215–236 (1995).

    CAS  Google Scholar 

  93. D. Ritter and C. Weisshaar, J. Am. Chem. Soc, 112, 6425–6426 (1990).

    Article  CAS  Google Scholar 

  94. J. J. Carroll, K. L. Haug, and J. C. Weisshaar, ibid., 115, 6962–6968 (1993).

    Article  CAS  Google Scholar 

  95. J. Milliken, T. M. Keller, A. P. Baronavsky, et al., Chem. Mater., 3, 386–387 (1991).

    Article  CAS  Google Scholar 

  96. C. I. Frum, R. Engleman, H. G. Hedderich, et al., Chem. Phys. Lett., 176, 504–508 (1991).

    Article  CAS  Google Scholar 

  97. Y. Huang and B. S. Freiser, J. Am. Chem. Soc, 113, 9418–9419 (1991).

    Article  CAS  Google Scholar 

  98. Zhao Wei, Chen Li-Quan, Li Yu-Xin, et al., Spectrochim. Acta, 50A, 1759–1767 (1994).

    Google Scholar 

  99. H. Yoshikawa, S. Kuroshima, I. Hirosawa, et al., Chem. Phys. Lett., 239, 103–106 (1995).

    Article  CAS  Google Scholar 

  100. G. P. Lopinski, j. R. Fox, and J. S. Lannin, Abstracts from the Materials Research Society Fall Meeting, Boston (1995), p. FF5.8.

  101. S. P. Solodovnikov, Izv. Ross. Akad. Nauk, Ser. Khim., 2, 303–304 (1997).

    Google Scholar 

  102. T. Pradeep, G. U. Kulkarni, K. R. Kannan, et al., J. Am. Chem. Soc, 114, 2272–2273 (1992).

    Article  CAS  Google Scholar 

  103. T. Kitamoto, S. Sasaki, H. Hashizume, et al., Photon Fact Activ Rept., Vol. 10, Tsukuba (1992), p. 216.

    Google Scholar 

  104. C. S. Yannoni, R. D. Johnson, G. Meijer, et al., J. Phys. Chem., 95, 9(1991).

    Article  CAS  Google Scholar 

  105. H. Nagashima, H. Yamaguchi, Y. Kato, et al., Chem. Lett., 12, 2153–2156 (1993).

    Article  Google Scholar 

  106. W. Kratschmer, K. Fostiropoulos, and D. R. Hoffman, Chem. Phys. Lett., 170, Nos. 2/3, 167–170 (1990).

    Article  Google Scholar 

  107. D. B. Powell, J. G. V. Scott, and N. Sheppard, Spectrochim. Acta, 28A, 327–335 (1972).

    Google Scholar 

  108. D. B. Powelland and T. J. Leedham, ibid., 337–341 (1972).

    Google Scholar 

  109. E. Maslovsky, Vibmtional Spectra of Organometallic Compounds, Wiley (1977), pp. 280-300.

  110. M. Wohlers, H. Werner, and R. Schlogi, Abstracts of Papers from the International Workshop “Fullerenes and Atomic Clusters” IWFAC-95, St. Petersburg (1993), p. 115.

  111. H. S. Chen, A. R. Kortan, R. S. Haddon, et al., J Phys. Chem., 96, 1016–1018 (1992).

    Article  CAS  Google Scholar 

  112. W. Kratschmer, L. D. Lamb, K. Fostiropoulos, et al.. Nature, 347, 354–358 (1990).

    Article  Google Scholar 

  113. H. S. Chen, A. R. Kortan, R. S. Haddon, et al., Appl. Phys. Lett., 59, No. 23, 2956–2958 (1991).

    Article  CAS  Google Scholar 

  114. J. Genesca and L. Victory, Rev. Coat. Corrvs., 24, 325 (1981).

    Google Scholar 

  115. J. Madarasz, G. Pokol, S. Keki, et al.. Carbon, 32, No. 5, 1023–1024 (1994).

    Article  CAS  Google Scholar 

  116. Y. Qicong, M. James, and C. Benjamin, J. Chem. Phys., 101, 2665–2672 (1994).

    Article  Google Scholar 

  117. A. L. Balch, J. W. Lee, B. C. Noll, et al., J. Chem. Soc, Chem. Commun., 56-58 (1993).

  118. V. N. Ivanova, V. A. Nadolinny, G. A. Mardezhova, et al., Abstracts of Papers from the 2nd International Interdisciplinary Colloquium on the Science and Technology of Fullerenes, Oxford (1996).

  119. R. E. Haufler, J. Conceicao, L. P. F. Chibante, et al., J. Phys. Chem., 94, 8634–8636 (1990).

    Article  CAS  Google Scholar 

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  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    V. N. Ivanova

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Translated from Zhumal Struktumoi Khimii, Vol. 41, No. I, pp. 164-181, January–February, 2000.

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Ivanova, V.N. Fullerene compounds with transition metals MnC60: Preparation, structure, and properties. J Struct Chem 41, 135–148 (2000). https://doi.org/10.1007/BF02684739

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