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Homologous series of layered tetradymite-like compounds in Bi-Te and GeTe-Bi2Te3 systems

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Abstract

Formation of the homologous series of layered compounds nBi2-mBi2Te3 and nGeTe mBi2Te3 is analyzed. For both series, the crystal structure contains two-layer (Bi2 or GeTe) and five-layer (Bi2Te3) packets perpendicular to the c axis. Unlike the Bi2 packets, the GeTe packets do not retain their individuality during crystal structure formation; they are linked to the Bi2Te3 five-layer packets to form new multilayer packets leading to a considerable change in the character of interatomic interactions.

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Authors and Affiliations

  1. A. A. Baikov Institute of Metallurgy, Russian Academy of Sciences. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    L. E. Shelimova, O. G. Karpinskii, V. I. Kosyakov, V. A. Shestakov, V. S. Zemskov & F. A. Kuznetsov

Authors
  1. L. E. Shelimova
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  2. O. G. Karpinskii
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  3. V. I. Kosyakov
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  4. V. A. Shestakov
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  5. V. S. Zemskov
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  6. F. A. Kuznetsov
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Translated from Zhumal Struktumoi Khimii, Vol. 41, No. 1, pp. 97-105, January–February, 2000.

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Shelimova, L.E., Karpinskii, O.G., Kosyakov, V.I. et al. Homologous series of layered tetradymite-like compounds in Bi-Te and GeTe-Bi2Te3 systems. J Struct Chem 41, 81–87 (2000). https://doi.org/10.1007/BF02684732

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  • DOI: https://doi.org/10.1007/BF02684732

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