Abstract
General features of the phase equilibria for binary and ternary systems formed by rare earth metals (REM or R) with Mn and other d-metals and p-elements (Me) are described and reviewed. On passing from the R−Mn alloys of the light REM to those of the heavy ones, a progressive change in the shape of the phase diagrams and an increasing stability of the intermediate phases (RMn2, RsMn23, and RMn12) is noticed. In particular, no compounds and a miscibility gap in the liquid state can be observed for La and Ce (which in this case behave like the alkaline earths). In the Pr−Mn and Nd−Mn systems no intermediate phases are stable down to room temperature. The peculiar trend of the R−Mn alloys is, moreover, compared with that exhibited by systems of transition metals close to manganese in the Periodic Table. In the ternary systems R−Mn−Me (the R−Mn−Al, R−Mn−Si and R−Mn−Ge ones were considered) and R−R′−Mn the dependence of the main phase equilibrium characteristics on the atomic radii of REM was observed, too. For the R−R′−Mn alloys a comparison is made between the experimental data (literature data and the authors' results) and those which can be predicted on the basis of the general alloying behavior of REM.
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References
L. Rolla andA. Iandelli, “Beitragen zur Kenntnis der Metalle der Seltenen und ihrer Legierungen. Die Legierurlgen des Lanthans mit Marlgan”, Berichte der Deutschen Chemischen Gesellschaft,75, 2091–2095 (1942).
A. Iandelli, “Le leghe fra Cerio e Manganese”, Atti Accad. Naz. Lincei, Cl. Sci. Fis. Mat. Nat., Rend.,13, 265–269 (1962).
R. L. Myklebust andA. H. Daane, “The yttrium-manganese system”, Trans. AIME,224, 354–357 (1962).
J. H. Wernick, S. E. Haszko andD. Dorsi, “Pseudo-binary systems involving rare earth Laves phases”, J. Phys. Chem. Solids,23, 567–572 (1962).
J. Thamer, “The system cerium-manganese in the range of 0–20 atomic per cent manganese”, J. Less-Common Met.,7, 341–346 (1964).
R. P. Elliott, “Laves phases of the rare earths with transition elements”, Proc. 4th Conf. Rare Earth Research, Phoenix (Arizona), 215–245 (1965).
M. Yu. Tesljuk, P. I. Kripyakevich andD. P. Frankevich, “New Laves phases containing manganese”, Kristallografiya,9, 469–470 (1965).
J. H. N. van Vucht andK. H. J. Buschow, “The structures of the rare earth trialuminides”, J. Less-Common Met.,10, 98–107 (1965).
H. R. Kirchmayr, “Aufbau der binaren Zustandsbilder von Gadolinium, Dysprosium, Holmium und Erbium mit Mangan”, Z. Metallkd.,58, 185–193 (1967).
H. R. Kirchmayr andW. Lugscheider, “Die Zustandsbilder Neodym-, Samarium-, und Terbium-Mangan,” ibid.,61, 22–23 (1970).
O. J. Emes-Misenko, “Investigation of the phase equilibria in the lanthanum-chromium-aluminum and lanthanum-manganese-aluminum systems in the region of low lanthanum content”, Visnik. Lviv. Univ. Ser. Khim., (12), 12–14 (1971).
H. Oesterreicher, “Structural and magnetic characteristics of the pseudobinary system PrMn2−ErMn2”, J. Less-Common Met.,23, 7–19 (1971).
C. Nair andH. Oesterreicher, “Structural and high magnetic studies of the systems PrMn2−GdMn2 and PrMn2−TbMn2”, ibid.,24, 237–242 (1971).
N. L. Eatough andH. T. Hall, “High-pressure synthesis of rare earth dimanganese compounds with the MgZn2 (Laves) structure”, Inorg. Chem.,11, 2608–2609 (1972).
L. Kaufman andH. Nesor, “Theoretical approaches to the determination of phase diagrams”, Ann. Rev. Mater. Sci.,3, 1–15 (1973).
K. H. J. Buschow, J. H. N. van Vucht, W. W. van den Hoogenhof, “Note on the crystal structure of the ternary rare earth-3d transition metal compounds of the type RT4Al8”, J. Less-Common Met.,50, 145–150 (1976).
I. Ansara, C. Bernard, L. Kaufman andP. Spencer, “A comparison of calculated phase equilibria in selected ternary alloy systems using thermodynamic values derived from different models”, Calphad,2, 1–15 (1978).
I. Felner, “Crystal structure of ternary rare earth-3d transition metal compounds of the RT6Al6 type”, J. Less-Common Met.,72, 241–249 (1980).
K. A. Gschneidner Jr., The Rare Earths in Modern Science and Technology, G. J. McCarthy, J. J. Rhyne, and H. B. Silber (eds.), Plenum, New York, Vol. 2 (1980), pp. 13–23.
A. V. Tsvyashchenko andS. V. Popova, “High pressure phases in the Mn−Yb system”, J. Less-Common Met.,90, 211–215 (1983).
Ja. M. Kalychak, O. I. Bodak andG. M. Chujko, “The systems Ce−Gd−Mn and Ce−Y−Mn”, Dopl. Akad. Nauk Ukr. RSR, Ser. B, (3), 39–42 (1984).
P. Rogl, “Phase equilibria in ternary and higher order systems with rare earth elements and silicon,” in: Handbook on the Physics and Chemistry of Rare Earths, K. A. Gschneidner Jr. and L. Eyring (eds.), North Holland, Amsterdam, Vol. 7 (1984).
A. Saccone, S. Delfino andR. Ferro, “Alloying behaviour of manganese with basic metals: Pr−Mn system”, J. Less-Common Met.,108, 89–105 (1985).
K. Shimisu, “NMR study in magnetically ordered state of rare earth-manganese laves phases”, J. Phys. Soc. Jpn.,54, 1154–1160 (1985).
H. Nakamura, H. Wada, K. Yoshimura, et al., “Effect of chemical pressure on the magnetism of YMn2: Magnetic properties of Y1−x Sc x Mn2 and Y1−x La x Mn2”, J. Phys. F: Metal Physics,18F, 981–991 (1988).
K. P. Belov, I. S. Dubenko, A. S. Markosyan andV. V. Snegirev “Magnetic properties of intermetallic compounds of the system Tb1−x Y x Mn2:(x−T) phase diagram”, Phys. Met. Metallogr.,67, 108–115 (1989).
E. I. Gladyshevsky, O. I. Bodak andV. K. Pecharsky, “Phase equilibria and crystal chemistry in ternary rare earths systems with metallic elements”, in: Handbook on the Physics and Chemistry of Rare Earths, K. A. Gschneidner Jr. and L. Eyring (eds.), North Holland, Amsterdam, Vol. 13 (1990).
S. I. Makhalenko andYu. B. Kuz'ma, “X-ray diffraction investigations of the Nd−Mn system”, Izv. Akad. Nauk SSSR, Neorg. Mater.,26(11), 2432–2433 (1990).
G. Petzow, G. Effenberg, et al., “Ternary alloys. A comprehensive compendium of evaluated constitutional data and phase diagrams”, VCH, Weinheim (Germany), 1990-1993, Vol. 3–8.
A. Saccone, S. Delfino andR. Ferro, “Systematics of rare earth-manganese alloys: Nd−Mn phase diagram”, Z. Metallkd.,84, 563–568 (1983).
H. Okamoto andT. B. Massalski, “Binary alloy phase diagrams requiring further studies”, J. Phase Equilibria,15, 500–521 (1994).
Yu. M. Prots, P. S. Salamakha, O. L. Sologub andO. I. Bodak, “The neodymium-(vanadium, chromium, manganese)-silicon systems”, J. Alloys and Compounds,215, 235–238 (1994).
A. Saccone, D. Maccio, and S. Delfino, “Phase equilibria in the manganese-yttrium system,” Perspectives in Inorganic Chemistry, Proc. XXIII Congr. Naz. Chimica Inorganica, Bressanone (Italy), 1994.
P. Villars, A. Prince, H. Okamoto, et al., “Handbook of ternary alloy phase diagrams,” ASM International, 1994.
G. Zanicchi, P. Riani, D. Mazzone et al., “On some ternary alloys R′−R″−Al with rare earths”, J. Alloys and Compounds,215, 181–186 (1994).
M. Giovannini, A. Saccone, R. Marazza andR. Ferro, “The isothermal section at 500°C of the Y−La−Mg system”, Metall. Mater. Trans.,26A, 5–10 (1995).
M. Giovannini, A. Saccone andR. Ferro, “Phase relationships at 500°C in the Y−Pr−Mg system”, J. Alloys and Compounds,220, 167–173 (1995).
H. Flandorfer, J. Grobner, A. Stamou, et al., “Experimental investigation and thermodynamic calculation of the ternary system Mn−Y−Zr,” Z. Metallkd. (1997).
H. Flandorfer, M. Giovannini, A. Saccone., et al., “The Ce−Mg−Y system,” Metall. Mater. Trans. (1997).
M. Giovannini, A. Saccone, H. Flandorfer, et al., “On the systematics of phase equilibria in complex magnesium-rare earth systems: Gd−Y−Mg system,” Z. Metallkd. (1997).
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Dipartimento di Chimica e Chimica Industriale, Sezione di Chimica Inorganica e Metallurgia, via Dodecaneso, 31-I-16146 Genova, Italy. Published in Poroshkovaya Metallurgiya, Nos. 3–4(394), pp. 1–12, March–April, 1997.
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Ferro, R., Saccone, A., Delfino, S. et al. Alloying behavior of the rare earth metals with manganese. Powder Metall Met Ceram 36, 117–127 (1997). https://doi.org/10.1007/BF02676075
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DOI: https://doi.org/10.1007/BF02676075