Skip to main content
Log in

Defect centers and degradation of GaP:N LED's

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

A new degradation property of N-doped GaP light emitting diodes has been found. Diodes Zn-diffused through a thin layer of SiO2 exhibit a complete saturation of the degradation process at 70 to 80 % of the initial light output. After saturation of the degradation process the emission spectrum is broadened on the low energy side. This broadening is identified as due to the formation of additional nearest neighbour N-pairs during degradation. Diodes diffused without a SiO2 cover show neither a saturation of the degradation process nor a change of the emission spectrum. Deep level transient spectroscopy revealed different defect levels for the two types of diodes, therefore different degradation properties might be expected.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. O'Hara, J. Phys. D: Appl. Phys.10 , 409 (1977).

    Article  Google Scholar 

  2. L. C. Kimerling and D. V. Lang, Lattice Defects in Semiconductors: Inst. Phys. Conf. Ser. No. 23, p. 589 (1974); D. V. Lang and L. C. Kimerling, Phys. Rev. Lett.33 , 489 (1974).

  3. G. B. Stringfellow, T. R. Cass and R. A. Burmeister, J. Electron. Mater.6 , 295 (1977).

    CAS  Google Scholar 

  4. D. V. Lang, J. Appl. Phys.45 , 3014 (1974).

    Article  CAS  Google Scholar 

  5. H. Lefèvre and M. Schulz, Appl. Phys.12 , 45 (1977).

    Article  Google Scholar 

  6. B. L. Smith, T. J. Hayes, A. R. Peaker and D. R. Wight, Appl. Phys. Lett.26 , 122 (1975).

    Article  CAS  Google Scholar 

  7. B. W. Wessels, J. Appl. Phys.48 , 1656 (1977).

    Article  CAS  Google Scholar 

  8. M. G. Craford, R. W. Shaw, A. H. Herzog and W. O. Groves, J. Appl. Phys.43 , 4075 (1972).

    Article  Google Scholar 

  9. D. V. Lang and L. C. Kimerling, Appl. Phys. Lett.28 , 248 (1976).

    Article  CAS  Google Scholar 

  10. For example, B. Molnar, J. Electrochem. Soc.123, 767 (1976).

    Article  CAS  Google Scholar 

  11. B. Tuck and P. R. Jay, J. Phys. D: Appl. Phys.10 , 1315 (1977).

    Article  CAS  Google Scholar 

  12. J. A. Van Vechten, J. Electron. Mater.4 , 1159 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schairer, W. Defect centers and degradation of GaP:N LED's. J. Electron. Mater. 8, 139–152 (1979). https://doi.org/10.1007/BF02663269

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02663269

Key words

Navigation