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Dissociation of cyclic amines and their N-trimethylsilyl derivatives under electron impact

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Study has been made of the mass spectra of ethyleneimine, azetidine, pyrolidine, piperidine, hexamethyleneimine, and their N-trimethylsilyl derivatives.

  2. 2.

    High-intensity peaks for molecular ions have been observed in the mass spectra of the imines; breakdown of these ions occurs through loss of H, C2H5, C2H3, and CH3 radicals, and C2H4 and H2 molecules.

  3. 3.

    Peaks for splinter ions containing silicon predominate in the mass spectra of the N-trimethylsilyl derivatives of the imines.

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Authors
  1. V. Yu. Orlov
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  2. V. V. Volkov
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  3. B. G. Zaikin
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  4. V. N. Perchenko
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  5. N. S. Nametkin
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Additional information

A. V. Topichev Institute for Petrochemical Syntheses, Academy of Sciences of the USSR, Moscow. L. Ya. Karpov Physicochemical Institute, Moscow. Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2251–2255, October, 1976.

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Orlov, V.Y., Volkov, V.V., Zaikin, B.G. et al. Dissociation of cyclic amines and their N-trimethylsilyl derivatives under electron impact. Russ Chem Bull 25, 2100–2104 (1976). https://doi.org/10.1007/BF02659525

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  • DOI: https://doi.org/10.1007/BF02659525

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